Tetrahedron p. 5979 - 5986 (1995)
Update date:2022-08-17
Topics:
Takeuchi
Kikuchi
Tsukamoto
Ishibashi
Kobayashi
Manzamenones J (1) and K (2) and plakoridine B (3), three new oxylipins with unique carbon-skeletons related to 3,6-dioxo-4-docosenoic acid, were isolated from Okinawan marine sponges, Plakortis spp., and their structures elucidated on the basis of spectral and chemical means. Absolute stereochemistry of manzamenone A (4) was investigated by applying the modified Mosher's method developed recently for secondary carboxylic acids by Kusumi.
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