Reversal of Diastereoselectivity in the BF3-Promoted Addition of Halobis(cyclopentadienyl)crotyltitanium Compounds to Aldehydes

DOI: 10.1021/jo00186a045

Source and publish data:

Journal of Organic Chemistry p. 2292 - 2293 (1984)

Update date:2022-08-17

Topics:

Authors:

Reetz, M. T.

Sauerwald, M.

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Article abstract of DOI:10.1021/jo00186a045

Diastereoselectivity in the reaction of halobis(cyclopentadienyl)crotyltitanium reagents with aldehydes is reversed if BF3 is added, erythro adducts being formed preferentially.

Full text of DOI:10.1021/jo00186a045

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