Bulletin of the Chemical Society of Japan p. 1341 - 1345 (1983)
Update date:2022-08-15
Topics:
Makimoto
Suzuki
Taniguchi
The hydrolysis rate of anionic esters of 3-nitro-4-acyloxybenzoic acids catalyzed by a cationic HTAB micelle was measured at the pressures up to 2 kbar at 25 C to obtain the pressure dependences of the substrate bindings and the micelle-catalyzed hydrolysis. The reaction mechanism is discussed in terms of the volume change for the formation of the micelle-ester complex and the activation volumes for the hydrolyis catalyzed by micelle.
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