Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 3069 - 3082 (1987)
Update date:2022-08-30
Topics:
Bird, Robert
Kemball, Charles
Leach, H. Frank
The hydrogenation of various alkenes, the equilibration of H2/D2 and the isomerization of some C6-alkenes have been studied over a range of temperatures on zirconia catalysts.Products from the reaction of some of the alkenes with deuterium were examined by (2)D n.m.r. spectroscopy.The rate of hydrogenation varied only to a small extent with the nature of the alkene, apart from some steric hindrance with some of the C6-compounds, and the supply of hydrogen to the surface appeared to be rate-determining.Reactions of alkenes with deuterium below 400 K gave D2-alkanes.As the temperature was raised, exchange of alkene was observed to an increasing extent, and the location of the deuterium atoms in the products provided evidence of possible mechanisms.
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