Journal of the Chemical Society. Chemical communications p. 456 - 457 (1981)
Update date:2022-08-16
Topics:
Hamilton, Robert
Mitchell, Thomas R. B.
Rooney, John J.
Hexa-1,5-diene is catalytically converted into acetone in an aqueous solution of (PhCN)2PdCl2, CuCl2, and CuCl at 60 deg C in the presence of oxygen, thereby revealing a hitherto unsuspected role of η3-allylic intermediates in both the PdII-catalysed Cope rearrangements of 1,5-dienes and the selective Wacker oxidation of propene and higher alk-1-enes to ketones.
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