Asymmetric hydroformylation of N-acyl 1-aminoacrylic acid derivatives by rhodium/chiral diphosphine catalysts

DOI: 10.1016/S0957-4166(00)86114-5

Source and publish data:

Tetrahedron Asymmetry p. 623 - 632 (1991)

Update date:2022-08-11

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Authors:

Gladiali

Pinna Pinna

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Article abstract of DOI:10.1016/S0957-4166(00)86114-5

The asymmetric hydroformylation of N-acylaminoacrylic acid esters 1 is efficiently catalysed by HRh(CO)(PPh₃)₃ in the presence of DIOP and related diphosphines as chiral ligands. The reaction is completely regioselective and affords

Full text of DOI:10.1016/S0957-4166(00)86114-5

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