Tetrahedron Letters p. 5117 - 5120 (1994)
Update date:2022-08-11
Topics:
Bantu, Nageshwer Rao
Kupfer, Rene
Brinker, Udo H.
The photolyses of anisole (1) and pentyl chloroacetate (2b) in isotropic media produce both alkylation products 3b-5b and dipentyl succinate (6b).In α- and β-CD complexes in aqueous solutions, 6b was absent and the o-alkylation product 3b was predominant.A cage effect and geometric control are attributed to the observed selective product distribution in α- and β-CD complexes in aqueous solutions.
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