A synthetic approach to benanomicin A. 1. Synthesis of 5,6-dihydrobenzo[a] naphthacenequinone

DOI: 10.7164/antibiotics.50.685

Source and publish data:

Journal of Antibiotics p. 685 - 689 (1997)

Update date:2022-08-11

Topics:

Authors:

Hirosawa, Sehei

Nishizuka, Toshio

Kondo, Shinichi

Ikeda, Daishiro

Takeuchi, Tomio

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Article abstract of DOI:10.7164/antibiotics.50.685

5,6-Dihydrobenzo[a] naphthacenequinone has been constructed by DIELS-ALDER reaction of an outer-ring diene with a naphthoquinone regioselectively. Similarly, the 14-hydroxy-5,6-dihydrobenzo[a] naphthacenequinone has also been synthesized via the reaction of vinylketene acetal with naphthoquinone.

Full text of DOI:10.7164/antibiotics.50.685

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