Journal of Physical Chemistry p. 8900 - 8908 (1993)
Update date:2022-08-30
Topics:
Tsentalovich, Yu. P.
Frantsev, A. A.
Doktorov, A. B.
Yurkovskaya, A. V.
Sagdeev, R. Z.
Photolysis of acetone in the presence of various hydrogen donors and of 3-hydroxy-3-methyl-2-butanone involves the formation of propan-2-olyl radicals which show both electron and nuclear spin polarization.The electron polarization of the radicals leads to additional nuclear polarization of the reaction products.Transfer of electron to nuclear polarization can occur by cross-relaxation and cross-correlation.The latter is descibed in detail.Experimentally, the mechanisms leads to a formation of net nuclear polarization for symmetrical radical pairs as well as an unusual kinetic behavior of multiplet effects.
View More
Chuzhou Baiao Biologhy S&T Co., Ltd.
Contact:+86-25-83212599；+86-25-83212699 13705185959
Address:Room 905, Tianzheng International Platza, No.399, Zhongyang Road ,Nanjing, Jiangsu Province, China
Contact:+36(21)2523420
Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
Puyang Willing Chemicals Co.,Ltd.
Contact:86-393-4840366
Address:Puyang Henan China
Zhenjiang Haitong Chemical Industry Co., Ltd.
Contact:+86 (511) 8448-0369
Address:Baoyan Town, Dantu District, Zhenjiang City, Jiangsu, China
Hangzhou Showland Technology Co., Ltd.
Contact:86-571-88920516
Address:ROOM2118,NO.553,WENSAN ROAD,HANGZHOU,CHINA
Doi:10.1134/S1070363216110153
()Doi:10.1023/A:1011311918880
(2000)Doi:10.1021/jm9602827
(1996)Doi:10.1016/j.tetasy.2011.10.017
(2011)Doi:10.1002/zaac.201400548
(2015)Doi:10.1021/acs.orglett.9b04599
(2020)
