Ozone and oxygen atom reactions with dimethylsulfide and methanethiol in argon matrices

Article abstract of DOI:10.1063/1.441636

Ground state oxygen atoms, generated by visible photolysis of ozone, have ben reacted with CH3SCH3 and CH3SH in argon matrices.For CH3SCH3, a stepwise addition to form DMSO and dimethylsulfone was observed.Methanethiol reactions with O atoms were more complex, leading to production of CH3SOH, CH3OSH, CH3S(O)H, and possibly CH3-SO2-H.These results are compared to the O + H2S reaction.The matrix results are also compared to gas phase studies where more extensive fragmentation has been observed, and inferences are drawn concerning the relative matrix deactivation ratesof the highly energetic sulfide-oxygen-atom precursor complex.

Full text of DOI:10.1063/1.441636

Ozone and oxygen atom reactions with dimethylsulfide and methanethiol in argon
matrices
D. E. Tevault, R. L. Mowery, and R. R. Smardzewski
Citation: The Journal of Chemical Physics 74, 4480 (1981); doi: 10.1063/1.441636
View online: http://dx.doi.org/10.1063/1.441636
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/74/8?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
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