Angewandte Chemie International Edition
10.1002/anie.202103969
RESEARCH ARTICLE
the one-shot intrablock crosslinking to contribute to the ultrahigh
resolution BCP lithography technology. The presented
[19]
Y. Liu, S. Pujals, P. J. M. Stals, T. Paulöhrl, S. I. Presolski, E. W.
Meijer, L. Albertazzi, A. R. A. Palmans, J. Am. Chem. Soc. 2018, 140,
3423–3433.
compartmentalization
protocol
of
one-shot
intrablock
[
[
20]
21]
H. Rothfuss, N. D. Knöfel, P. W. Roesky, C. Barner-Kowollik, J. Am.
Chem. Soc. 2018, 140, 5875–5881.
crosslinking offers novel perspectives in the single-chain
technology field, facilitating the advancement of biomimetic
polymer chemistries and related material sciences.
Y. Bai, X. Feng, H. Xing, Y. Xu, B. K. Kim, N. Baig, T. Zhou, A. A.
Gewirth, Y. Lu, E. Oldfield, et al., J. Am. Chem. Soc. 2016, 138,
11077–11080.
[
[
22]
23]
T. Terashima, J. Oleo Sci. 2020, 69, 529-538.
J. Chen, E. S. Garcia, S. C. Zimmerman, Acc. Chem. Res. 2020, 53,
Acknowledgements
1244-1256.
[
24]
A. Sanchez-Sanchez, S. Akbari, A. J. Moreno, F. Lo Verso, A. Arbe, J.
Colmenero, J. A. Pomposo, Macromol. Rapid Commun. 2013, 34,
1681–1686.
This work was financially supported by the MEXT Grant-in-Aid
for Research Activity Start-up (to T.I.; Grant No. 26888001),
Grant-in-Aid for Young Scientists (B) (to T.I.; Grant No.
[
[
25]
26]
Y. Bai, H. Xing, G. A. Vincil, J. Lee, E. J. Henderson, Y. Lu, N. G.
Lemcoff, S. C. Zimmerman, Chem. Sci. 2014, 5, 2862–2868.
C. C. Cheng, F. C. Chang, H. C. Yen, D. J. Lee, C. W. Chiu, Z. Xin,
ACS Macro Lett. 2015, 4, 1184–1188.
1
5K17862), Grant-in-Aid for Scientific Research (B) (to T.S.;
Grant No. 19H02769), and the Photoexcitonix Project and
Creative Research Institute of Hokkaido University (to T.S.). K.
[27]
E. Verde-Sesto, A. Arbe, A. J. Moreno, D. Cangialosi, A. Alegría, J.
Colmenero, J. A. Pomposo, Mater. Horiz. 2020, 7, 2292-2313.
M. A. J. Gillissen, I. K. Voets, E. W. Meijer, A. R. A. Palmans, Polym.
Chem. 2012, 3, 3166–3174.
W. received funding from
a JSPS Fellowship for Young
[
[
[
[
28]
29]
30]
31]
Scientists. This work was, in part, performed under the approval
of the Photon Factory Program Advisory Committee (Proposals
L. Delafresnaye, N. Zaquen, R. P. Kuchel, J. P. Blinco, P. B.
Zetterlund, C. Barner-Kowollik, Adv. Funct. Mater. 2018, 28, 1800342.
C. Heiler, S. Bastian, P. Lederhose, J. P. Blinco, E. Blasco, C. Barner-
Kowollik, Chem. Commun. 2018, 54, 3476–3479.
2
017G589 and 2019G579). The authors thank Mr. Toshiaki Ito
(
Hokkaido University, Japan) for his assistance with the TEM
experiment.
J. Steinkoenig, M. M. Zieger, H. Mutlu, C. Barner-Kowollik,
Macromolecules 2017, 50, 5385–5391.
Keywords: block copolymers • intramolecular crosslinking •
Janus-shaped single-chain nanoparticles • compartmentalization
[32]
C.-J. Tsai, S. Kumar, B. Ma, R. Nussinov, Protein Sci. 1999, 8, 1181–
1190.
[
33]
J. Markl, Biochim. Biophys. Acta 2013, 1834, 1840–1852.
•
microphase separation
[
[
34]
35]
C. M. Dobson, Nature 2003, 426, 884−890.
S. F. M. van Dongen, H.-P. M. de Hoog, R. J. R. W. Peters, M. Nallani,
[
[
[
[
[
1]
H. R. Kiricheldorf, J. Polym. Sci. Part A: Polym. Chem. 2010, 48, 251–
R. J. M. Nolte, J. C. M. van Hest, 2009, 109, 6212–6274.
Z. Li, E. Kesselman, Y. Talmon, M. A. Hillmyer, T. P. Lodge, Science
[
36]
2
84.
Z. Jia, M. J. Monteiro, Polym. Sci. Part A: Polym. Chem. 2012, 50,
085–2097.
D. E. Lonsdale, M. J. Monteiro, Polym. Sci. Part A: Polym. Chem.
011, 49, 4603–4612.
T. Yamamoto, S. Yagyu, Y. Tezuka, J. Am. Chem. Soc. 2016, 138,
904–3911.
2004, 306, 98–101.
2]
3]
4]
5]
2
[37]
R. Chandrawati, M. P. Van Koeverden, H. Lomas, F. Caruso, J. Phys.
Chem. Lett. 2011, 2, 2639–2649.
[
[
[
38]
39]
40]
A. H. Gröschel, F. H. Schacher, H. Schmalz, O. V. Borisov, E. B.
Zhulina, A. Walther, A. H. E. Müller, Nat. Commun. 2012, 3, DOI
2
10.1038/ncomms1707.
3
A. Belluati, S. Thamboo, A. Najer, V. Maffeis, C. von Planta, I. Craciun,
Y. Satoh, H. Matsuno, T. Yamamoto, K. Tajima, T. Isono, T. Satoh,
Macromolecules 2017, 50, 97–106.
C. G. Palivan, W. Meier, Adv. Funct. Mater. 2020, 30, DOI
10.1002/adfm.202002949.
[
[
6]
7]
Y. Tezuka, A. Tsuchitani, H. Oike, Macromolecules 2003, 36, 65–70.
J. Jeong, K. Kim, R. Lee, S. Lee, H. Kim, H. Jung, M. A. Kadir, Y. Jang,
H. B. Jeon, K. Matyjaszewski, et al., Macromolecules 2014, 47, 3791–
R. K. Roy, J. F. Lutz, J. Am. Chem. Soc. 2014, 136, 12888–12891.
Z. Cui, L. Huang, Y. Ding, X. Zhu, X. Lu, Y. Cai, ACS Macro Lett. 2018,
[41]
7, 572–575.
3796.
[
[
42]
43]
Z. Cui, H. Cao, Y. Ding, P. Gao, X. Lu, Y. Cai, Polym. Chem. 2017, 8,
3755–3763.
[
8]
Y. Mato, K. Honda, K. Tajima, T. Yamamoto, T. Isono, T. Satoh, Chem.
Sci. 2019, 10, 440–446.
M. Matsumoto, T. Terashima, K. Matsumoto, M. Takenaka, M.
Sawamoto, J. Am. Chem. Soc. 2017, 139, 7164–7167.
M. Matsumoto, M. Sawamoto, T. Terashima, ACS Macro Lett. 2019, 8,
[
[
9]
M. Gauthier-Jaques, P. Theato, ACS Macro Lett. 2020, 9, 700–705.
T. Noda, Y. Doi, Y. Ohta, S. ichi Takata, A. Takano, Y. Matsushita, J.
Polym. Sci. 2020, 58, 2098–2107.
10]
[44]
3
20–325.
[
[
[
[
[
11]
12]
13]
14]
15]
C. K. Lyon, A. Prasher, A. M. Hanlon, B. T. Tuten, C. A. Tooley, P. G.
Frank, E. B. Berda, Polym. Chem. 2015, 6, 181–197.
S. Mavila, O. Eivgi, I. Berkovich, N. G. Lemcoff, Chem. Rev. 2016, 116,
[
45]
L. Jiang, M. Xie, J. Dou, H. Li, X. Huang, D. Chen, ACS Macro Lett.
2018, 7, 1278–1282.
[
[
46]
47]
X. Ji, Y. Zhang, H. Zhao, Chem. Eur. J. 2018, 24, 3005–3012.
F. Lang, D. Xiang, J. Wang, L. Yang, Y. Qiao, Z. Yang,
Macromolecules 2020, 53, 2271–2278.
878–961.
E. Harth, B. Van Horn, V. Y. Lee, D. S. Germack, C. P. Gonzales, R. D.
Miller, C. J. Hawker, J. Am. Chem. Soc. 2002, 124, 8653–8660.
N. Hosono, M. A. J. Gillissen, Y. Li, S. S. Sheiko, A. R. A. Palmans, E.
W. Meijer, J. Am. Chem. Soc. 2013, 135, 501–510.
[
48]
K. Kyoda, T. Yamamoto, Y. Tezuka, J. Am. Chem. Soc. 2017, 141,
7526–7536.
I. Perez-Baena, I. Asenjo-Sanz, A. Arbe, A. J. Moreno, F. Lo Verso, J.
Colmenero, J. A. Pomposo, Macromolecules 2014, 47, 8270–8280.
R. Chen, E. B. Berda, ACS Macro Lett. 2020, 9, 1836–1843.
H. Frisch, B. T. Tuten, C. Barner-Kowollik, Israel J. Chem. 2020, 60,
[49]
K. Watanabe, R. Tanaka, K. Takada, M. J. Kim, J. S. Lee, K. Tajima, T.
Isono, T. Satoh, Polym. Chem. 2016, 7, 4782–4792.
[
[
50]
51]
R. Tanaka, K. Watanabe, T. Yamamoto, K. Tajima, T. Isono, T. Satoh,
Polym. Chem. 2017, 8, 3647–3656.
[
[
16]
17]
K. Watanabe, S. Katsuhara, H. Mamiya, T. Yamamoto, K. Tajima, T.
Isono, T. Satoh, Chem. Sci. 2019, 10, 3330–3339.
86-99.
[
18]
J. A. Pomposo, “Single-Chain Polymer Nanoparticles: Synthesis,
Characterization, Simulations, and Applications” Wiley-VCH (2017).
[52]
K. Watanabe, S. Katsuhara, H. Mamiya, Y. Kawamura, T. Yamamoto,
K. Tajima, T. Isono, T. Satoh, Nanoscale 2020, 12, 16526–16534.
6
This article is protected by copyright. All rights reserved.