Journal of Molecular Structure p. 159 - 164 (1980)
Update date:2022-08-11
Topics:
Bett, W.
Cradock, S.
Rankin, D. W. H.
The structure of silyl formate, HCOOSiH3, in the gas phase is determined by electron diffraction.The principal bond lengths and angles (ra) are r(Si-O) = 169.5 +/- 0.3 pm, r(C-O) = 131.5 +/- 0.6 pm, r(C=O) = 120.9 +/- 0.7 pm, (C-O-Si) angle = 116.8 +/- 0.5 deg, (O=C-O) angle = 123.5 +/- 0.5 deg.The silyl group is twisted by 21 deg away from the planar cis conformation but there is nevertheless a very short (286.5 +/- 1.0 pm) non-bonded Si...O contact.
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