LIQUID PHASE CO-AMMONOLYSIS OF PHENOL AND CYCLOHEXANOL WITH PALLADIUM-ON-CARBON CATALYST

DOI: 10.1246/cl.1980.239

Source and publish data:

Chemistry Letters p. 239 - 240 (1980)

Update date:2022-08-11

Topics:

Authors:

Hamada, Hideaki

Yamamoto, Makoto

Matsuzaki, Takehiko

Wakabayashi, Katsuhiko

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Article abstract of DOI:10.1246/cl.1980.239

In the presence of Pd/C catalyst, phenol and cyclohexanol are aminated simultaneously to aniline and cyclohexylamine by ammonolysis, while conversion of phenol or cyclohexanol alone is very poor.It is suggested that this amination is caused by hydrogen transfer between phenol and cyclohexanol.Ru/C, Rh/C, and Pt/C are ineffective for this co-amination.

Full text of DOI:10.1246/cl.1980.239

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