Chemistry Letters p. 239 - 240 (1980)
Update date:2022-08-11
Topics:
Hamada, Hideaki
Yamamoto, Makoto
Matsuzaki, Takehiko
Wakabayashi, Katsuhiko
In the presence of Pd/C catalyst, phenol and cyclohexanol are aminated simultaneously to aniline and cyclohexylamine by ammonolysis, while conversion of phenol or cyclohexanol alone is very poor.It is suggested that this amination is caused by hydrogen transfer between phenol and cyclohexanol.Ru/C, Rh/C, and Pt/C are ineffective for this co-amination.
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