Journal of the Chemical Society. Perkin transactions I p. 1837 - 1842 (1992)
Update date:2022-08-17
Topics:
Suginome, Hiroshi
Nakayama, Yutaka
Senboku, Hisanori
A new transformation of steroids into 18-norsteroids under mild conditions is described.The key step was a regioselective β-scission of the alkoxyl radicals generated by photolysis of the hypoiodite of 18-hydroxy-18,20α-epoxy steroids, prepared by photoly
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