The electrophilic trifluoromethyl radical CF3 · Application of the dual-parameter equation to the correlation analysis of relative rates of the trifluoromethylbromo addition reactions to 14 p-Y-substituted phenylacetylenes

DOI: 10.1016/S0022-1139(96)03482-3

Source and publish data:

Journal of Fluorine Chemistry p. 133 - 138 (1996)

Update date:2022-08-11

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Authors:

Jiang, Xi-Kui

Ji, Guo-Zhen

Xie, John Rong-Yuan

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Article abstract of DOI:10.1016/S0022-1139(96)03482-3

A rigorous procedure was applied to the measurement of the relative rates, i.e., k_r(Y)=k_Y/k_H, of the trifluoromethylbromo addition reactions to 14 p-Y-substituted phenylacetylenes (1-Y, with Y=F, Cl, Br, Me, ^tBu

Full text of DOI:10.1016/S0022-1139(96)03482-3

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