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New Journal of Chemistry
DOI: 10.1039/C7NJ03559D
COMMUNICATION
Journal Name
binding affinity of CB[7]-PNIPAM were investigated and 17.
compared with CB[7] pendent copolymer. Different from CB[7]
Y. Ahn, Y. Jang, N. Selvapalam, G. Yun and K. Kim, Angew.
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8.
pendent copolymer, the LCST of CB[7]-PNIPAM was about 1.5
o
3
C higher than N -PNIPAM, and loading with guest molecule
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9.
with greater charge in the cavity of CB[7] led to higher LCST.
Similarly, CB[7]-PNIPAM inherited the high binding affinity of
CB[7]. Better yet, the CB[7] moiety of CB[7]-PNIPAM was
efficiently used. The CB[7] terminal PNIPAM will be useful in
the construction of supramolecular graft and block
copolymers.
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0.
21.
22.
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33, 17966-17976.
Conflicts of interest
L. Cao and L. Isaacs, Org. Lett., 2012, 14, 3072-3075.
B. Vinciguerra, L. Cao, J. R. Cannon, P. Y. Zavalij, C.
Fenselau and L. Isaacs, J. Am. Chem. Soc., 2012, 134,
2
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There are no conflicts to declare.
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3133-13140.
D. W. Lee, K. M. Park, B. Gong, D. Shetty, J. K. Khedkar, K.
Baek, J. Kim, S. H. Ryu and K. Kim, Chem Commun (Camb),
Acknowledgements
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015, 51, 3098-3101.
This work was supported by grants from National Natural
Science Foundation of China (21374055).
D. W. Lee, K. M. Park, M. Banerjee, S. H. Ha, T. Lee, K. Suh,
S. Paul, H. Jung, J. Kim, N. Selvapalam, S. H. Ryu and K.
Kim, Nature chemistry, 2011, 3, 154-159.
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