Archiv der Pharmazie p. 153 - 156 (1982)
Update date:2022-08-16
Topics:
Hartke, Klaus
Zerbe, Horst-Georg
The reaction of antimony pentachloride with thioanisole (5) at -70 deg C leads to the formation of the sulfonium salt 6, whereas at 0 deg C the chlorosulfonium salt 7 is formed.Under similar conditions 4-methylthioanisole (9) is converted into the expected chlorosulfonium salt 10, which decomposed, however, during isolation experiments.
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