Tetrahedron Letters p. 1381 - 1384 (1983)
Update date:2022-08-30
Topics:
Hebert, E.
Welvart, Z.
Ghelfenstein, M.
Szwarc, H.
The pressure increase from 0,1 to 1000 MPa decreases the rate, but does not change the stereoselectivity of the Wittig rearrangement of the 2-octyl benzhydryl ether in HMPT.These results rule out any contribution of a concerted process to the observed stereoselectivity (29percent).
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