Tetrahedron Letters p. 4423 - 4426 (1985)
Update date:2022-08-11
Topics:
Moret, Etienne
Schlosser, Manfred
Under carefully chosen working conditions (solvent, temperature), methyltitanium reagents smoothly convert homoallyl alcohols having a terminal double-bond into (E)-3-penten-1-ols whereas non-terminal 3-alken-1-ols afford 4-methyl-branched derivatives with configurational inversion of the chain (Z -> E; E -> Z), stereoselectivities being better than 99percent.
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