Inorganic Chemistry
Article
iron together support exceptional oxidative reactivity. The
limits of this reactivity will be explored in future studies.
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ASSOCIATED CONTENT
Supporting Information
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̈
*
S
4
IR spectra for complexes 1−10, UV vis spectra for compounds
1
, 2, 5, and 9, crystallographic details for complexes 1−10 and
Stich, T. A.; Yano, J.; Britt, R. D.; Chang, C. J. J. Am. Chem. Soc. 2012,
134, 1536−1542.
19) Rohde, J.-U.; Stubna, A.; Bominaar, E. L.; Munck, E.; Nam, W.;
̈
3
1
structures of 6, 7a, 7b, 9, and 10. P NMR spectra for
(
phosphine oxidation reactions. Computational details for
t
−
t
Que, L., Jr. Inorg. Chem. 2006, 45, 6435−6445.
20) Seo, M. S.; Kim, N. H.; Cho, K. B.; So, J. E.; Park, S. K.;
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[
Fe(O Bu) (O)] and LiFe(O Bu) (O), calculated frontier
3
3
(
orbital splitting diagrams, calculated spin density plots, and
́
(
E. V. Inorg. Chem. 2012, 51, 5006−5021.
(22) Hirao, H.; Kumar, D.; Que, L., Jr.; Shaik, S. J. Am. Chem. Soc.
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AUTHOR INFORMATION
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(
23) Janardanan, D.; Wang, Y.; Schyman, P.; Que, L., Jr.; Shaik, S.
*
Angew. Chem., Int. Ed. 2010, 49, 3342−3345.
24) England, J.; Guo, Y.; Farquhar, E. R.; Young, V. G.; Mu
Que, L., Jr. J. Am. Chem. Soc. 2010, 132, 8635−8644.
25) England, J.; Guo, Y.; Van Heuvelen, K. M.; Cranswick, M. A.;
Rohde, G. T.; Bominaar, E. L.; Munck, E.; Que, L., Jr. J. Am. Chem. Soc.
2011, 133, 11880−11883.
26) Gupta, R.; Lacy, D. C.; Bominaar, E. L.; Borovik, A. S.;
Hendrich, M. P. J. Am. Chem. Soc. 2012, 134, 9775−9784.
27) Betley, T. A.; Wu, Q.; Van Voorhis, T.; Nocera, D. G. Inorg.
Present Addresses
Department of Chemistry, Wayne State University, Detroit
(
̈
nck, E.;
§
Michigan 48202, United States.
(
∥
Department of Chemistry, University of Texas at El Paso, El
̈
Paso, Texas 79968.
(
Notes
The authors declare no competing financial interest.
(
Chem. 2008, 47, 1849−1861.
ACKNOWLEDGMENTS
This research was supported by the NSF (Grant CHE-
112154). Grants from the NSF also provided instrument
support to the DCIF at MIT (CHE−9808061, DBI−9729592.
S.G. and D.V. acknowledge the support of the Dreyfus
Foundation for Dreyfus Postdoctoral Fellowships in Environ-
mental Chemistry. We thank Profs. C. C. Cummins and T. A.
Betley for helpful discussions, and Dr. Wayne Lo for assistance
with MS data.
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dx.doi.org/10.1021/ic302634q | Inorg. Chem. XXXX, XXX, XXX−XXX