Journal of the Chemical Society. Perkin transactions II p. 1763 - 1768 (1990)
Update date:2022-08-17
Topics:
Eichinger, Peter C.H.
Bowie, John H.
Deprotonation of alkyl vinyl ethers (CH2=CHOR) with NH2- in the gas phase yields the two carbanions CH2=C(-)OR and C(-)H=CHOR.The former ion can be synthesized specifically using the SN2(Si) reaction CH2=C(SiMe3)OR + NH2- --> CH2=C(-)OR + Me3SiNH2: the ion undergoes several competitive and characteristic collision-induced reactions.For example, (i) when R >/= Et, elimination of an alkene, i.e.CH2=C(-)OR --> (CH2CHO)- + R-H, and (ii) the Wittig rearrangement CH2=C(-)OR --> CH2=C(R)O-.
View More
Changsha Goomoo Chemical Technology Co.Ltd
Contact:+86-731-82197655
Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
Contact:+86-13032617415
Address:china
Shandong Jincheng Zhonghua Bio-pharmaceutical Co.,Ltd
Contact:+86-533-5415882
Address:Zichuan Economic Development Zone,Zibo City,Shandong Province,China
Beijing Mesochem Technology Co.,LTD
website:http://www.mesochem.com
Contact:0086-10-57862036
Address:2301, Floor 23, Building 9 Lippo Plaza, Yard 8 Ronghua Middle Road, ETDZ, Beijing, China
Contact:+86-371-67759225
Address:No.32, Jinsuo Road, High-tech Zone
Doi:10.1134/S1070363220060134
()Doi:10.1016/j.tetlet.2005.04.007
(2005)Doi:10.1021/jo01052a080
(1962)Doi:10.1021/ie50574a027
(1957)Doi:10.1016/j.tetlet.2018.03.011
(2018)Doi:10.1007/s11164-020-04364-9
(2021)
