ASYMMETRYSCHE KATALYSEN. XXXII. ENANTIOSELEKTIVE PHENYLIERUNG VON cis-CYCLOHEXAN-1,2-DIOL UND meso-BUTAN-2,3-DIOL

DOI: 10.1016/0022-328X(86)82093-9

Source and publish data:

Journal of Organometallic Chemistry p. C1 - C3 (1986)

Update date:2022-08-11

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Authors:

Brunner, Henri

Obermann, Uwe

Wimmer, Peter

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Article abstract of DOI:10.1016/0022-328X(86)82093-9

The monophenylation of cis-cyclohexan-1,2-diol and meso-butan-2,3-diol with triphenylbismuth diacetate gives cis- 1-phenoxycyclohexan-2-ol and2-phenoxybutan-3-ol, respectively.In the presence of catalysts consisting of Cu(OAc)2 and opticallly active pyridine oxazoline ligands, optical inductions of up to 30 percent ee are attained.

Full text of DOI:10.1016/0022-328X(86)82093-9

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