One Pot Synthesis of Dinuclear Tungsten(V) Compounds Containing 2+ (X = O, S; Y = O, S) Cores by Thermally Induced Internal Electron-Transfer Processes

Article abstract of DOI:10.1246/bcsj.61.2265

New synthetic methods for the preparation of dimeric tungsten(V) complexes are described containing the core ²⁺ (X = O, S; Y = O, S).The synthesized complexes have been characterized by a variety of spectroscopic techniques. has been found to react with cyanide to give