Tetrahedron Letters p. 833 - 836 (1985)
Update date:2022-08-10
Topics:
Dhimane, H.
Pommelet, J. C.
Chuche, J.
Lhommet, G.
Richaud, M. G.
Haddad, M.
Azabicyclic enaminones were obtained in good yield by flash vacuum pyrolysis of aminomethylene Meldrum's acid derivates.The reaction involves a -1,4 H shift from aminomethyleneketene intermediate followed by electrocyclisation of delocalized azomethine ylide.
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