SYNTHETIC STUDIES ON ARENE-OLEFIN CYCLOADDITIONS - Vll: A THREE-STEP TOTAL SYNTHESIS OF (+/-)-SILPHINENE.

DOI: 10.1016/S0040-4039(00)98120-6

Source and publish data:

Tetrahedron Letters p. 2625 - 2628 (1985)

Update date:2022-08-16

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Authors:

Wender, Paul A.

Ternansky, Robert J.

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Article abstract of DOI:10.1016/S0040-4039(00)98120-6

A three-step total synthesis of (+/-)-silphinene (1) is described which illustrates the high process selectivity attainable with the arene-olefin metaphotocycloaddition and a method for selective transformation of metacycloadducts.

Full text of DOI:10.1016/S0040-4039(00)98120-6

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