Reaction of Nucleophiles with Bridgehead Carbocations Derived from 1-Bromobicyclooctanes and 1-Bromobicyclononanes

DOI: 10.1021/jo00223a035

Source and publish data:

Journal of Organic Chemistry p. 4605 - 4608 (1985)

Update date:2022-07-31

Topics:

Authors:

Kraus, George A.

Hon, Yung-Son

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00223a035

Both intramolecular and intermolecular reactions of bridgehead carbocations are described.The carbocations are best generated from the corresponding halide with silver triflate.The carbocations reacted effectively with allyltrimethylsilane, ethyl acetoacetate, benzene, and enol silyl ethers.Bridgehead radicals were also examined.

Full text of DOI:10.1021/jo00223a035

Products guided by the article

Product name:1-fluorobicyclo<3.3.1>nonan-3-one

Cas No:98577-35-6

R&D Labs maybe for 98577-35-6

SHANGHAI RC CHEMICALS CO.,LTD.

website:http://www.rcc.net.cn

Contact:+86-21-50322175

Address:Rm1415 Yinqiao Masion No.58 Jinxin Road Pudong Shanghai China
Shandong Xingshun New Material Co., Ltd.

website:http://www.sd-xingshun.com

Contact:+86-519-86461196

Address:Middle of Luhua East Road, Dingtao District
Yingkou Sanzheng Organic Chemical Co. Ltd.

Contact:+86-417-3638818

Address:25 Gengxinli Village, Daqing Road, Yingkou, Liaoning, China
Shanghai FWD Chemicals ltd

website:http://www.fwdchem.com

Contact:86-21-54450828

Address:Room 802,Lotus Tower ,159 Tianzhou Road,Xuhui District,Shanghai
Taizhou volsen chemical Co., Ltd

website:http://www.volsenchem.com

Contact:+86-576-88869393

Address:Jiaojiang District, Taizhou, Zhejiang, China.

Relevant to this article

A new general method for the preparation of metal carbene complexes [13]

Doi:10.1021/ja0157393
(2001)
Acyclic Stereoselection using 1,2-Asymmetric Induction. The First Total Synthesis of (+)-Corynomycolic Acid

Doi:10.1039/c39850000498
(1985)
Synthesis of phosphono analogs of 2-O-acetyl-1-O-hexadecyl(octadecyl)-sn-3-glycerylphosphorylcholine (platelet-activating factor)

Doi:10.1002/ardp.19853180806
(1985)
Doi:10.1002/hlca.19490320102
(1949)
Synthesis of purpuroine A, nakirodin A and MDN-0104: The hidden puzzles and risk of error in their configurational assignments

Doi:10.1016/j.tet.2017.01.029
(2017)
Regiospecific deuteriation and tritiation of various drugs using a homogeneous rhodium trichloride catalyst

Doi:10.1002/jps.2600800917
(1991)

Article Doi