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Gallium arsenide

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Gallium arsenide

EINECS 215-114-8
CAS No. 1303-00-0 Density 5.316 g/cm3
PSA 0.00000 LogP -0.31160
Solubility < 0.1 g/100 mL (20 °C) in water Melting Point 1238 °C
Formula GaAs Boiling Point N/A
Molecular Weight 144.645 Flash Point N/A
Transport Information UN 1557 Appearance Gray cubic crystals
Safety 20/21-28-45-60-61 Risk Codes 23/25-50/53
Molecular Structure Molecular Structure of 1303-00-0 (GALLIUM ARSENIDE) Hazard Symbols ToxicT; DangerousN
Synonyms

Galliumarsenide;Gallium monoarsenide;Gallium monoarsenide (GaAs);

Article Data 1

Gallium arsenide Consensus Reports

Reported in EPA TSCA Inventory. Arsenic and its compounds are on the Community Right-To-Know List.

Gallium arsenide Standards and Recommendations

OSHA PEL: OSHA: Cancer Hazard
ACGIH TLV: TWA 0.01 mg(As)/m3; Human Carcinogen; BEI: 35 µ (As)/L inorganic arsenic and methylated metabolites in urine
NIOSH REL: (Gallium Arsenide) CL 0.002 mg(As)/m3/15M

Gallium arsenide Specification

The Gallium arsenide, with the CAS registry number 1303-00-0 and EINECS registry number 215-114-8, has the systematic name and IUPAC name of arsanylidynegallium. And the molecular formula of this chemical is GaAs. It is kind of gray cubic crystals, and belongs to the following product categories: Inorganics; Electronic Materials; Materials Science; Micro/Nanoelectronics; Arsenides; Ceramics; Metal and Ceramic Science.

The physical properties of Gallium arsenide are as following: (1)ACD/LogP: 2.32; (2)# of Rule of 5 Violations: 0; (3)#H bond acceptors: 2; (4)#H bond donors: 1; (5)#Freely Rotating Bonds: 0; (6)Polar Surface Area: 28.72 Å2; (7)Index of Refraction: 1.674; (8)Molar Refractivity: 42.8 cm3; (9)Molar Volume: 113.9 cm3; (10)Polarizability: 16.96×10-24cm3; (11)Surface Tension: 61.5 dyne/cm; (12)Density: 1.24 g/cm3; (13)Flash Point: 121.9 °C; (14)Enthalpy of Vaporization: 59.46 kJ/mol; (15)Boiling Point: 350 °C at 760 mmHg; (16)Vapour Pressure: 4.51E-05 mmHg at 25°C.

Preparation of Gallium arsenide: It can be prepared by direct reaction from the elements which is used in a number of industrial processes. For example, VPE reaction of gaseous gallium metal and arsenic trichloride:
2 Ga + 2 AsCl3 → 2 GaAs + 3 Cl2

Uses of Gallium arsenide: It can be used to produce light emission devices(LCD), LD, FRT, HEMT, HTB, MMIC, MIMIC, HSIC and solar cells and detectors.

You should be cautious while dealing with this chemical. It is toxic by inhalation and in contact with skin. It is also very toxic to aquatic organisms, and may cause long-term adverse effects in the aquatic environment. Therefore, you had better take the following instructions: When using, do not eat, drink or smoke; After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer); In case of accident or if you feel unwell, seek medical advice immediately (show label where possible); This material and/or its container must be disposed of as hazardous waste; Avoid release to the environment. Refer to special instructions safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: [As]#[Ga]
(2)InChI: InChI=1/As.Ga/rAsGa/c1-2
(3)InChIKey: JBRZTFJDHDCESZ-WMDPQSSYAY

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 4700mg/kg (4700mg/kg) PERIPHERAL NERVE AND SENSATION: FLACCID PARALYSIS WITHOUT ANESTHESIA (USUALLY NEUROMUSCULAR BLOCKAGE)

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: FOOD INTAKE (ANIMAL)
Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 45(10), Pg. 13, 1980.
rat LD30 intraperitoneal 10gm/kg (10000mg/kg) BEHAVIORAL: EXCITEMENT

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION
Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 24(3), Pg. 45, 1980.

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