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Hydrazoic acid

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Name

Hydrazoic acid

EINECS 231-965-8
CAS No. 7782-79-8 Density 1.09(25/4oC)
PSA 61.24000 LogP 0.42796
Solubility

Stability

    Unstable. Violently explosive in the concentrated orpure states. Readily forms explosive compounds with heavy metals.This is a dangerous and hard to handle substance which must not beprepared or handled by non-experts.<
Melting Point -80oC
Formula HN3 Boiling Point 37oC
Molecular Weight 43.028 Flash Point N/A
Transport Information N/A Appearance N/A
Safety Poison by intraperitoneal route. Mildly toxic by inhalation. A severe irritant to skin, eyes, and mucous membranes. Continued inhalation causes central nervous system problems in humans (changes in EEG, somnolence, cough, headache, change in heart rate, fall in blood pressure, collapse, chills, and fever). High concentrations can cause fatal convulsions. Chronic exposure has been reported to cause injury to kidneys and spleen, hypotension, palpitation, ataxia, weakness. A dangerously sensitive explosive hazard when shocked or exposed to heat. Reacts with heavy metals to form very unstable heavy metal azides. Reacts violently with Cd, Cu, Ni, HNO3, F2. When heated to decomposition it emits toxic fumes of NOx. See also AZIDES. Risk Codes N/A
Molecular Structure Molecular Structure of 7782-79-8 (Hydrazoic acid) Hazard Symbols Dangerous explosion risk when shocked or heated. Strong irritant to eyes and mucous membranes. TLV: CL 0.1 ppm (vapor)
Synonyms

Azidicacid; Azoimide; Diazoimide; Hydrogen azide; Hydronitric acid; Triazoic acid

Article Data 247

Hydrazoic acid Chemical Properties

IUPAC: Diazonioazanide
CAS:7782-79-8
The Molecular formula of Hydrazoic acid (7782-79-8):HN3
The Molecular Weight of Hydrazoic acid (7782-79-8):43.02804
EINECS:231-965-8
Melting Point: −80oC
Boiling Point:37oC
Appearance:colorless, highly volatile liquid
Density:1.09 g/cm3
Stability:Unstable. Violently explosive in the concentrated or pure states. Readily forms explosive compounds with heavy metals. This is a dangerous and hard to handle substance which must not be prepared or handled by non-experts.
Mol File:7782-79-8.mol

Hydrazoic acid Toxicity Data With Reference

1.    

ihl-hmn TCLo:300 ppb:CNS,BRN,CVS

    JIHTAB    Journal of Industrial Hygiene and Toxicology. 30 (1948),98.
2.    

ihl-rat LCLo:1100 ppm/1H

    PHRPA6    Public Health Reports. 58 (1943),607.
3.    

ipr-mus LD50:22 mg/kg

    JIHTAB    Journal of Industrial Hygiene and Toxicology. 30 (1948),98.

Hydrazoic acid Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Hydrazoic acid Safety Profile

Poison by intraperitoneal route. Mildly toxic by inhalation. A severe irritant to skin, eyes, and mucous membranes. Continued inhalation causes central nervous system problems in humans (changes in EEG, somnolence, cough, headache, change in heart rate, fall in blood pressure, collapse, chills, and fever). High concentrations can cause fatal convulsions. Chronic exposure has been reported to cause injury to kidneys and spleen, hypotension, palpitation, ataxia, weakness. A dangerously sensitive explosive hazard when shocked or exposed to heat. Reacts with heavy metals to form very unstable heavy metal azides. Reacts violently with Cd, Cu, Ni, HNO3, F2. When heated to decomposition it emits toxic fumes of NOx. See also AZIDES.

Safty informations about Hydrazoic acid (7782-79-8):
RIDADR:0473
HazardClass:1.1A

Hydrazoic acid Standards and Recommendations

ACGIH TLV: CL 0.1 ppm (vapor)
DFG MAK: 0.1 ppm (0.18 mg/m3)

Hydrazoic acid Specification

 Hydrazoic acid (7782-79-8) can be soluble in the strongest acids to produce explosive salts. It is also called for Hydrazoic acid ; Azoimide ; Hydrogen azide ; Hydrazoic acid (as vapour) ; 1H-triazirine ; Hydronitric acid ; Triazoic acid . This is a dangerous and hard to handle substance which must not be prepared or handled by non-experts. It has a pungent smell and its vapor can cause violent headaches. It is highly soluble in water and can be soluble in Alkali , Alcohol , Ether .

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