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Iodofenphos

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Iodofenphos

EINECS 242-069-1
CAS No. 18181-70-9 Density 1.871g/cm3
PSA 69.59000 LogP 5.14470
Solubility 0.1mg/L(20 oC) Melting Point 72-73° (Beriger); mp 75° (Haddow)
Formula C8H8 Cl2 I O3 P S Boiling Point 375.7°Cat760mmHg
Molecular Weight 413 Flash Point 181°C
Transport Information N/A Appearance N/A
Safety Moderately toxic by ingestion and skin contact. Used as a pesticide. When heated to decomposition it emits very toxic fumes of Cl, I, POx, and SOx. See also CHLOROPHENOLS. Risk Codes 21-50/53
Molecular Structure Molecular Structure of 18181-70-9 (IODOFENPHOS) Hazard Symbols
Synonyms

Alfacron; C9491; CIBA C 9491; Ciba 9491; Iodofenfos; Iodofenphos; Iodophos; Jodfenphos;Monocron 9491; Nuvanol N; O,O-Dimethyl O-(2,5-dichloro-4-iodophenyl)phosphorothioate; O-(2,5-Dichloro-4-iodophenyl) O,O-dimethyl phosphorothioate;OMS 1211; Trix

Article Data 3

Iodofenphos Chemical Properties

Molecular Structure of Iodofenphos (CAS NO. 18181-70-9):

EINECS: 242-069-1
IUPAC Name: (2,5-Dichloro-4-iodophenoxy)-dimethoxy-sulfanylidene-$l^{5}-phosphane 
Molecular Formula: C8H8Cl2IO3PS
Molecular Weight: 412.996551 g/mol
XLogP3: 5.5
H-Bond Donor: 0
H-Bond Acceptor: 3
Canonical SMILES: COP(=S)(OC)OC1=CC(=C(C=C1Cl)I)Cl
InChI: InChI=1S/C8H8Cl2IO3PS/c1-12-15(16,13-2)14-8-4-5(9)7(11)3-6(8)10/h3-4H,1-2H3
InChIKey: LFVLUOAHQIVABZ-UHFFFAOYSA-N
Index of Refraction: 1.623
Molar Refractivity: 77.88 cm3
Molar Volume: 220.6 cm3
Surface Tension: 56.1 dyne/cm
Density: 1.871 g/cm3
Flash Point: 181 °C
Enthalpy of Vaporization: 59.88 kJ/mol
Boiling Point: 375.7 °C at 760 mmHg
Vapour Pressure: 1.65E-05 mmHg at 25 °C
Water Solubility: 0.0501 mg/L at 25 °C
Storage Temp.: APPROX 4 °C
BRN: 1885795

Iodofenphos Toxicity Data With Reference

1.    

orl-rat LD50:2000 mg/kg

    GUCHAZ    Guide to the Chemicals Used in Crop Protection 5 (1968),197.
2.    

skn-rat LD50:2150 mg/kg

    SPEADM    Special Publication of the Entomological Society of America. 78-1 (1974),45.
3.    

orl-mus LD50:3 g/kg

    85DPAN    Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel Werner Perkow,Berlin, Germany.: Verlag Paul Parey,1971/76.
4.    

orl-dog LD50:3 g/kg

    85DPAN    Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel Werner Perkow,Berlin, Germany.: Verlag Paul Parey,1971/76.
5.    

orl-rbt LD50:2 g/kg

    85DPAN    Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel Werner Perkow,Berlin, Germany.: Verlag Paul Parey,1971/76.
6.    

skn-rbt LD50:500 mg/kg

    85DPAN    Wirksubstanzen der Pflanzenschutz und Schadlingsbekampfungsmittel Werner Perkow,Berlin, Germany.: Verlag Paul Parey,1971/76.

Iodofenphos Consensus Reports

Chlorophenol compounds are on The Community Right-To-Know List.

Iodofenphos Safety Profile

Safety Information of Iodofenphos (CAS NO. 18181-70-9):
Hazard Codes: Xn Harmful,N Dangerous
Risk Statements: 21-50/53
R21:Harmful in contact with skin
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
Safety Statements: 36/37-60-61
S36/37:Wear suitable protective clothing and gloves
S60:This material and its container must be disposed of as hazardous waste
S61:Avoid release to the environment. Refer to special instructions / safety data sheets
RIDADR: UN2811 6.1/PG 3
RTECS: TF0175000
Moderately toxic by ingestion and skin contact. Used as a pesticide. When heated to decomposition it emits very toxic fumes of Cl, I, POx, and SOx. See also CHLOROPHENOLS.

Iodofenphos Specification

  Iodofenphos with cas registry number of 18181-70-9 is also called for AI3-27408 ; Alfacron ; C 9491 ; C-9491 ; Caswell No. 309B ; Ciba C-9491 ; Ciba-Geigy C-9491 ; Compound C-9491 ; ENT 27408 ; EPA Pesticide Chemical Code 309700 ; HSDB 1568 ; Iodofenphos [BAN] ; Iodofenphos [BSI:ISO] ; Iodofenfos ; Iodophenphos ; Iodophos ; Jodfenphos ; Jodfenphos [ISO] ; Monocron 9491 ; NSC 190998 ; Nuvanol N ; O,O-Dimethyl-O-(2,5-dichlor-4-jodphenyl)-monothiophosphat ; O,O-Dimethyl-O-(2,5-dichlor-4-jodphenyl)-monothiophosphat [German] ; O,O-Dimethyl-O-(2,5-dichlor-4-jodphenyl)-thionophosphat ; O,O-Dimethyl-O-(2,5-dichlor-4-jodphenyl)-thionophosphat [German] ; O,O-Dimethyl-O-2,5-dichloro-4-iodophenyl thiophosphate ; O-(2,5-Dichloro-4-iodophenyl) O,O-dimethyl phosphorothioate ; O-(2,5-Dichloro-4-iodophenyl)-O,O-dimethyl phosphorothioate ; OMS-1211 ; Phenol, 3,4-dichloro-, O-ester with O-methyl methylphosphoramidothioate ; Phosphorothioic acid, O-(2,5-dichloro-4-iodophenyl) O,O-dimethyl ester ; Trix ; UNII-SME6G1846X .

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