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LEAD ACID ARSENATE

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Name

LEAD ACID ARSENATE

EINECS 232-064-2
CAS No. 7784-40-9 Density 5.79
PSA 83.42000 LogP -1.67500
Solubility

Stability

Toxicology

    Toxic if inhaled, swallowed or absorbed through the skin. Cumulative poison.Reproductive toxin. Carcinogenic. Added to the ECHA Candidate List of Substances of VeryHigh Concern for au
Melting Point ca. 280 C (decomposes)
Formula AsH3 O4 . Pb Boiling Point N/A
Molecular Weight 347.12 Flash Point N/A
Transport Information N/A Appearance N/A
Safety Confirmed human carcinogen. A poison by ingestion. Used as an insecticide and herbicide. When heated to decomposition it emits very toxic fumes of As and Pb. See also ARSENIC COMPOUNDS and LEAD COMPOUNDS. Risk Codes R45; R61; R23/25; R33; R50/53; R62
Molecular Structure Molecular Structure of 7784-40-9 (LEAD ARSENATE) Hazard Symbols Highly toxic. TLV: 0.15 mg/m3; a carcinogen.
Synonyms

Leadarsenate (PbHAsO4) (6CI,7CI); Acid lead arsenate; Arsenic acid lead salt; Leadacid arsenate; Lead arsenate; Lead hydrogen arsenate (PbHAsO4); Lead(2+)monohydrogen arsenate

 

LEAD ACID ARSENATE Chemical Properties

MF: AsHO4Pb
MW: 347.13
APPEARANCE: ODOURLESS WHITE HEAVY POWDER
Melting point (decomposes): about 280°C
Relative density (water=1): 5.79

LEAD ACID ARSENATE Toxicity Data With Reference

1.   

orl-rat LD50:100 mg/kg

   PCOC**    Pesticide Chemicals Official Compendium ,Association of the American Pesticide Control Officials, Inc.(Topeka, KS.: )1966,653.
2.   

orl-mus LD50:1526 mg/kg

   GISAAA    Gigiena i Sanitariya. 51 (1)(1986),74.
3.   

ipr-mus LD50:128 mg/kg

   GISAAA    Gigiena i Sanitariya. 51 (1)(1986),74.
4.   

orl-rbt LD50:100 mg/kg

   JPIFAN    Japan Pesticide Information.(3)(1970),5.
5.   

orl-ckn LD50:450 mg/kg

   PCOC**    Pesticide Chemicals Official Compendium ,Association of the American Pesticide Control Officials, Inc.(Topeka, KS.: )1966,653.

LEAD ACID ARSENATE Consensus Reports

IARC Cancer Review: Human Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 23 , 1980,p. 39.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 1 , 1972,p. 40.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 1 , 1972,p. 40.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Arsenic and its compounds, as well as lead and its compounds, are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

LEAD ACID ARSENATE Safety Profile

Hazard Codes: T,N
Risk Statements: 45-61-23/25-33-50/53-62
Safety Statements: 53-45-60-61

Confirmed human carcinogen. A poison by ingestion. Used as an insecticide and herbicide. When heated to decomposition it emits very toxic fumes of As and Pb. See also ARSENIC COMPOUNDS and LEAD COMPOUNDS.

LEAD ACID ARSENATE Standards and Recommendations

OSHA PEL: TWA 0.05 mg(Pb)/m3; 0.01 mg(As)/m3; Cancer Hazard
ACGIH TLV: TWA 0.01 mg/m3; Confirmed Human Carcinogen; BEI: 35 μ (As)/L inorganic arsenic and methylated metabolites in urine
NIOSH REL: (Inorganic Lead) TWA 0.10 mg(Pb)/m3; (Inorganic Arsenic) CL 0.002 mg(As)/m3/15M
DOT Classification:  6.1; Label: Poison

LEAD ACID ARSENATE Specification

STORAGE: Provision to contain effluent from fire extinguishing. Separated from food and feedstuffs. Well closed.
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