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Lead carbonate

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Lead carbonate

EINECS 209-943-4
CAS No. 598-63-0 Density 6.6 g/cm3
PSA 63.19000 LogP -2.82780
Solubility soluble in acid and alkali, but insoluble in alcohol and ammonia Melting Point 399-401°C (dec.))
Formula CH2O3·Pb Boiling Point 333.6 °C at 760 mmHg
Molecular Weight 267.21 Flash Point 169.8 °C
Transport Information UN 3077 9/PG 3 Appearance white powder
Safety 53-45-60-61 Risk Codes 61-20/22-33-50/53-62
Molecular Structure Molecular Structure of 598-63-0 (Lead(II) carbonate) Hazard Symbols ToxicT,DangerousN
Synonyms

Cerussite;Dibasic lead carbonate;Lead(2+)carbonate;Plumbous carbonate;

 

Lead carbonate Consensus Reports

IARC Cancer Review: Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 23 , 1980,p. 325.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 1 , 1972,p. 40.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Lead and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Lead carbonate Standards and Recommendations

OSHA PEL: TWA 0.05 mg(Pb)/m3
ACGIH TLV: TWA 0.15 mg(Pb)/m3
NIOSH REL: (Inorganic Lead) TWA 0.10 mg(Pb)/m3

Lead carbonate Specification

The Lead carbonate, with the CAS registry number 598-63-0, is also known as Dibasic lead carbonate. It belongs to the product categories of Inorganics; Chemical Synthesis; Lead Salts; LeadMetal and Ceramic Science; Salts; ACS Grade Chemical Synthesis; Catalysis and Inorganic Chemistry; Essential Chemicals; Lead; Routine Reagents. Its EINECS number is 209-943-4. This chemical's molecular formula is CH2O3·Pb and molecular weight is 267.21. What's more, its systematic name is potassium lead(2+) carbonate. Its classification codes are: (1)Human Data; (2)Reproductive Effect; (3)Tumor data. It is stable at common pressure and temperature, and it should be sealed and stored in a cool and dry place. It is used as in organic synthesis. It is also used in chemical analysis and preparing paints, pigments and in photography industry. 

Physical properties of Lead carbonate are: (1)ACD/LogP: -0.81; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -1.98; (4)ACD/LogD (pH 7.4): -3.77; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 3; (10)#H bond donors: 2; (11)#Freely Rotating Bonds: 0; (12)Polar Surface Area: 57.53 Å2; (13)Flash Point: 169.8 °C; (14)Enthalpy of Vaporization: 63.37 kJ/mol; (15)Boiling Point: 333.6 °C at 760 mmHg; (16)Vapour Pressure: 2.58E-05 mmHg at 25°C.

Preparation: this chemical can be prepared by treating an aqueous slurry of lead oxide with acetic acid in the presence of air and carbon dioxide or by shaking a suspension of a lead salt less soluble than the carbonate with ammonium carbonate at a low temperature to avoid formation of basic lead carbonate.

PbO + CO2 → PbCO3

When you are using this chemical, please be cautious about it as the following:
This chemical is harmful by inhalation and if swallowed. It has a danger of cumulative effects. It is very toxic to aquatic organisms as it may cause long-term adverse effects in the aquatic environment. It may cause harm to the unborn child. Moreover, it has a possible risk of impaired fertility. In case of accident or if you feel unwell, you must seek medical advice immediately (show the label where possible). It should be avoided exposure that you need obtain special instructions before use. This material and its container must be disposed of as hazardous waste. You must avoid releasing it to the environment just refering to special instructions/safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: C(=O)([O-])[O-].[Pb+2]
(2)Std. InChI: InChI=1S/CH2O3.Pb/c2-1(3)4;/h(H2,2,3,4);/q;+2/p-2
(3)Std. InChIKey: MFEVGQHCNVXMER-UHFFFAOYSA-L

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LDLo oral 1gm/kg (1000mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
human LDLo oral 571mg/kg (571mg/kg) BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

GASTROINTESTINAL: NAUSEA OR VOMITING
International Polymer Science and Technology. Vol. 3, Pg. 93, 1976.
man TDLo oral 214mg/kg/4W (214mg/kg) GASTROINTESTINAL: CONTRACTION (ISOLATED TISSUE)

LIVER: "JAUNDICE, OTHER OR UNCLASSIFIED"
New England Journal of Medicine. Vol. 303, Pg. 459, 1980.

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