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Lead chromate

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Lead chromate

EINECS 231-846-0
CAS No. 7758-97-6 Density 6.3 g/cm3
PSA 80.26000 LogP -0.85600
Solubility Insoluble in water Melting Point 844 °C
Formula PbCrO4 Boiling Point N/A
Molecular Weight 323.19 Flash Point N/A
Transport Information UN 3077 9/PG 3 Appearance yellow to orange powder
Safety 53-45-60-61 Risk Codes 61-33-40-50/53-62
Molecular Structure Molecular Structure of 7758-97-6 (Lead chromate) Hazard Symbols ToxicT, DangerousN
Synonyms

RoyalYellow 6000;Leadchromate(VI) (PbCrO4) (7CI);Chromium lead oxide (CrPbO4);Lead chromate;Leadchromate (PbCrO4);Lead chromium oxide (PbCrO4);Plumbous chromate;

 

Lead chromate Chemical Properties

IUPAC Name: Dioxido(dioxo)chromium; lead(2+) 
Following is the structure of Lead chromate (CAS NO.7758-97-6):
                 
Molecular formula: PbCrO4
Molar mass: 323.2 g/mol 
EINECS: 231-846-0
Melting point: 844 °C
Density: 6.3 g/cm3
Water Solubility: Insoluble. <0.1 g/100 mL at 19 ºC
Stability: Stable. Reacts violently with ferric ferrocyanide.
Appearance of Lead chromate (CAS NO.7758-97-6): orange-yellow powder
Product Categories of Lead chromate (CAS NO.7758-97-6): Inorganics; Analytical Reagents for General Use; E-L, Puriss p.a. ACS; Puriss p.a. ACS; ACS GradeChemical Synthesis; Catalysis and Inorganic Chemistry; Essential Chemicals; Lead; Routine Reagents
Canonical SMILES: [O-][Cr](=O)(=O)[O-].[Pb+2]
InChI: InChI=1S/Cr.4O.Pb/q;;;2*-1;+2
InChIKey: MOUPNEIJQCETIW-UHFFFAOYSA-N

Lead chromate Uses

 Lead chromate is used in some pyrotechnic compositions, especially delay compositions, as an oxidizer. Up to the late 1800s it was used to impart a bright yellow color to some types of candy.
Previously, its use was wider. Lead chromate and "white lead", or lead carbonate, were the most common lead-based paint pigments.

Lead chromate Toxicity Data With Reference

1.    

cyt-hmn:lym 13 µmol/L

    MUREAV    Mutation Research. 77 (1980),157.
2.    

mnt-mus-ipr 500 mg/kg

    TJEMAO    Tohoku Journal of Experimental Medicine. 146 (1985),373. TUMOAB    Tumori. 57 (1971),213.
3.    

orl-mus LD50:>12 g/kg

    OYYAA2    Oyo Yakuri. Pharmacometrics. 2 (1968),76.
4.    

ipr-gpg LD75:156 mg/kg

    MEIEDD    Merck Index. 10 (1983),777.

Lead chromate Consensus Reports

NTP 10th Report on Carcinogens. IARC Cancer Review: Group 1 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 , 1987,p. 165.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 2 , 1973,p. 100.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 23 , 1980,p. 205.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Human Sufficient Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 23 , 1980,p. 205.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Lead and its compounds, as well as chromium and its compounds, are on the Community Right-To-Know List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Lead chromate Safety Profile

Confirmed carcinogen with experimental neoplastigenic and tumorigenic data. Poison by intraperitoneal route. Mildly is toxic by ingestion. Human mutation data reported. Potentially explosive reactions with azodyestuffs (e.g., dinitroaniline orange, chlorinated para red). Violent reaction with aluminum + dinitronaphthalene + heat. Forms pyrophoric mixtures with sulfur, tantalum, and iron(III) hexacyanoferrate(4−) (e.g., brunswick green pigment, prussian blue pigment). When heated to decomposition it emits toxic fumes of Pb. See also LEAD COMPOUNDS and CHROMIUM COMPOUNDS.
Hazard Codes: ToxicT,DangerousN
Risk Statements: 61-33-40-50/53-62 
R61:May cause harm to the unborn child. 
R33:Danger of cumulative effects. 
R40:Limited evidence of a carcinogenic effect. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R62:Risk of impaired fertility.
Safety Statements: 53-45-60-61 
S53:Avoid exposure - obtain special instructions before use. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 3077 9/PG 3
WGK Germany: 3
RTECS: GB2975000
HazardClass: 6.1
PackingGroup: III
Hazardous Substances: Data 7758-97-6(Hazardous Substances Data)

Lead chromate Standards and Recommendations

OSHA PEL: TWA 0.05 mg(Pb)/m3; CL 0.1 mg(CrO3)/m3
ACGIH TLV: 0.05 mg(Cr)/m3; Human Carcinogen
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
NIOSH REL: (Chromium(VI)) TWA 0.001 mg(Cr(VI))/m3; (Inorganic Lead) TWA 0.10 mg(Pb)/m3

Lead chromate Analytical Methods

For occupational chemical analysis use NIOSH: Chromium Hexavalent, 7024.

Lead chromate Specification

 Lead chromate , its cas register number is 7758-97-6. It also can be called Chromate de plomb ; Chromate de plomb [French] ; Lead chromate (PbCrO4) ; Lead chromate(VI) ; Lead(II) chromate ; Phoenicochroite ; and Plumbous chromate . Its classification code are Agricultural Chemical; Insecticide; Mutation data; TSCA Flag S [Substance is identified in a proposed or final SNUR (Significant New Use Rule) under TSCA] and Tumor data.

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