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| CAS No.: | 583-15-3 |
|---|---|
| Name: | MERCURIC BENZOATE |
| Molecular Structure: | |
|
|
|
| Formula: | C7H6 O2 . 1/2 Hg |
| Molecular Weight: | 442.821 |
| Synonyms: | Benzoicacid, mercury(2+) salt (8CI,9CI); Mercury benzoate (6CI,7CI); Mercuricbenzoate; Mercury(II) benzoate; b-Mercuribenzoate |
| Melting Point: |
166-167 °C(lit.) |
| Boiling Point: | 249.3°C at 760 mmHg |
| Flash Point: | 111.4°C |
| Solubility: | 1.2 g/100mL H2O (15°C), 2.5g/100mL H2O (100°C) [CRC10] |
| Hazard Symbols: | Toxic by ingestion, inhalation, and skin absorption; strong irritant. TLV: TWA 0.1 mg(Hg)/m3. |
| Risk Codes: | R26/27/28; R33; R50/53 |
| Safety: | A poison. When heated to decomposition it emits toxic fumes of Hg. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC. |
| PSA: | 52.60000 |
| LogP: | 2.61290 |
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Chemistry
The IUPAC name of Mercuric benzoate (CAS NO.583-15-3): mercury(2+) dibenzoate
Synonyms: Benzoicacid , Mercury(2+)salt ; Beta-mercuribenzoate ; Mercurydibenzoate ; Mercury(II) benzoate ; Mercury benzoate ; Mercuric benzoate ; Quecksilber(II)-benzoat ; Dibenzoic acid mercury(II) salt
CAS: 583-15-3
EINECS: 209-499-1
Molecular Formula: C14H10HgO4
Formula Weight: 442.82 g/mol
Molecular Structure:
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Melting point:166-167 °C(lit.)
Flash Point: 111.4 °C
Boiling Point: 249.3 °C at 760 mmHg
General Description: A white crystalline odorless solid. Melting point 165°C. Sensitive to light. Highly toxic by inhalation and ingestion.
Air & Water: Reactions Slightly soluble in water.
Consensus Reports
Mercury and its compounds are on the Community Right-To-Know List.
Safety Profile
The Hazard Codes of Mercuric benzoate (CAS NO.583-15-3): 
T+
N
Risk Statements:R26/27/28:Very toxic by inhalation, in contact with skin and if swallowed. R33:Danger of cumulative effects. R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements:S13:Keep away from food, drink and animal foodstuffs. S28:After contact with skin, wash immediately with plenty of soap-suds. S36:Wear suitable protective clothing. S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S60:This material and its container must be disposed of as hazardous waste. S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
Health Hazard: TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated.
A poison. When heated to decomposition it emits toxic fumes of Hg. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC.
Standards and Recommendations
OSHA PEL: CL 0.1 mg(Hg)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin); BEI: 35 µg/g creatinine total inorganic mercury in urine preshift; 15 µg/g creatinine total inorganic mercury in blood at end of shift at end of workweek.
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (skin)
DOT Classification: 6.1; Label: Poison