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Mercuric iodide

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Name

Mercuric iodide

EINECS 231-873-8
CAS No. 7774-29-0 Density 6.36
PSA 0.00000 LogP -5.99450
Solubility potassium iodide solution: passes test Melting Point 259 °C(lit.)
Formula HgI2 Boiling Point 127 °C at 760 mmHg
Molecular Weight 454.399 Flash Point 350°C subl.
Transport Information UN 2025 6.1/PG 2 Appearance red solid
Safety 13-28-45-60-61 Risk Codes 26/27/28-33-50/53
Molecular Structure Molecular Structure of 7774-29-0 (MERCURY(II) IODIDE) Hazard Symbols VeryT+,DangerousN
Synonyms

Diiodomercury;Mercuric diiodide;Mercury diiodide;Mercury(2+) diiodide;Mercury(2+) iodide;Mercury(II) iodide;Red Mercuric Iodide;Mercury iodide (HgI2);

 

Mercuric iodide Chemical Properties

IUPAC:  Diiodomercury
 Mercury(II) iodide (7774-29-0) is also called for  EINECS 231-873-8 ; HSDB 1211 ; Hydrargyrum bijodatum ; Hydrargyrum diodatum ; Mercuric iodide ; Mercuric iodide, red ; Mercurius bijodatus ; Mercury biniodide ; Mercury diiodide ; Mercury iodide (HgI2) ; Red mercuric iodide ; alpha-Mercury(II) iodide and so on.
Molecular Formula: HgI2
Molecular Weight: 454.4
EINECS: 231-873-8
Enthalpy of Vaporization: 19.76 kJ/mol 
Boiling Point: 127°C at 760 mmHg 
Vapour Pressure: 13.8 mmHg at 25°C 
Heavy Atom Count: 3
Formal Charge: 0
Complexity: 2.8
Isotope Atom Count: 0
Defined Atom StereoCenter Count: 0
Undefined Atom StereoCenter Count: 0
Defined Bond StereoCenter Count: 0
Undefined Bond StereoCenter Count: 0
Covalently-Bonded Unit Count: 1 
The appearance of  Mercury(II) iodide (7774-29-0)  is red-orange crystal.
The molecular structure of  Mercury(II) iodide (7774-29-0):

Mercuric iodide Uses

1.In medicine, Mercury(II) iodide (7774-29-0) is formerly used as a treatment for syphilis.
2.In veterinary medicine, Mercury(II) iodide (7774-29-0) is used in blister ointments in exostoses, bursal enlargement and so on.
3. Mercury(II) iodide (7774-29-0) is used for preparation of  Nessler's reagent, used for detection of  presence of  ammonia.
4. Mercury(II) iodide (7774-29-0) is a semiconductor material, used in some x-ray and gamma ray detection and imaging devices operating at room temperatures.

Mercuric iodide Toxicity Data With Reference

1.    

orl-man LDLo:357 mg/kg

    ZKMEAB    Zeitschrift fuer Klin Medicine. 106 (1927),783.
2.    

orl-rat LD50:18 mg/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 25 (7)(1981),27.
3.    

skn-rat LD50:75 mg/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 25 (7)(1981),27.
4.    

orl-mus LD50:17 mg/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 25 (7)(1981),27.
5.    

ipr-mus LD50:4200 µg/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 25 (7)(1981),27.

Mercuric iodide Consensus Reports

Mercury and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory.

Mercuric iodide Safety Profile

A human poison by ingestion. Poison experimentally by ingestion, skin contact, and intraperitoneal routes. An experimental teratogen. Violent reaction with chlorine trifluoride. When heated to decomposition it emits very toxic fumes of Hg and I. See also MERCURY COMPOUNDS, INORGANIC; MERCURY COMPOUNDS, ORGANIC and IODIDES.
Hazard Codes:  T+Very ,N Dangerous
Risk Statements:  26/27/28-33-50/53 
R26/27/28:Very toxic by inhalation, in contact with skin and if swallowed. 
R33:Danger of cumulative effects. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements:  13-28-45-60-61 
S13:Keep away from food, drink and animal foodstuffs. 
S28:After contact with skin, wash immediately with plenty of soap-suds. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR:  UN 2025 6.1/PG 2
WGK Germany:  3
RTECS:  OW5250000
F:  8
HazardClass:  6.1
PackingGroup:  II

Mercuric iodide Standards and Recommendations

OSHA PEL: CL 0.1 mg(Hg)/m3 (skin)
ACGIH TLV: TWA 0.1 mg(Hg)/m3 (skin); BEI: 35 µg/g creatinine total inorganic mercury in urine preshift; 15 µg/g creatinine total inorganic mercury in blood at end of shift at end of workweek.
NIOSH REL: (Mercury, Aryl and Inorganic) CL 0.1 mg/m3 (skin)

Mercuric iodide Specification

1.Reactivity Profile
 Mercury(II) iodide (7774-29-0) is a mild reducing agent. Reacts with sodium azide to form mercury(II) azide, which is shock, friction, and heat sensitive. Incompatible with acetylene, ammonia, chlorine dioxide, azides, chlorine trifluoride, calcium (because of amalgam formation), sodium carbide, lithium, rubidium, copper .

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