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Basic Information
CAS No.: 14168-44-6
Name: Methylenedinitramine
Molecular Structure:
Molecular Structure of 14168-44-6 (Methylenedinitramine)
Formula: CH4 N4 O4
Molecular Weight: 136.067
Synonyms: 1,3-Dinitro-1,3-diazapropane;MEDINA; MEDINA (explosive); Methylene dinitramine; N,N'-Dinitromethanediamine
Density: 1.542g/cm3
Boiling Point: 323.4°Cat760mmHg
Flash Point: 149.4°C
Safety: A powerful and sensitive explosive. It explodes when heated to 217°C. The lead salt explodes at 195°C. Upon decomposition it emits toxic fumes of NOx.
PSA: 115.70000
LogP: 0.33470
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Chemistry

The Molecular Structure of Methylene dinitramine (CAS NO.14168-44-6):
Molecular Formula: CH4N4O4 
Molecular Weight: 136.0669  
IUPAC: N-(nitramidomethyl)nitramide
ACD/LogP: -0.43 
ACD/LogD (pH 5.5):  -1.61 
ACD/LogD (pH 7.4):  -3.14 
ACD/BCF (pH 5.5): 1 
ACD/BCF (pH 7.4): 1 
ACD/KOC (pH 5.5): 1 
ACD/KOC (pH 7.4): 1 
Index of Refraction: 1.499 
Molar Refractivity: 25.91 cm3 
Molar Volume: 88.2 cm3 
Surface Tension: 59.4 dyne/cm 
Density: 1.542 g/cm3 
Flash Point: 149.4 °C 
Enthalpy of Vaporization: 56.53 kJ/mol 
Boiling Point: 323.4 °C at 760 mmHg 
Vapour Pressure:  0.000263 mmHg at 25°C

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 190mg/kg (190mg/kg)   Pharmaceutical Chemistry Journal Vol. 10, Pg. 1504, 1976.

Safety Profile

A powerful and sensitive explosive. It explodes when heated to 217°C. The lead salt explodes at 195°C. Upon decomposition it emits toxic fumes of NOx.

Specification

 Methylene dinitramine (CAS NO.14168-44-6) is also called as 4-01-00-03059 (Beilstein Handbook Reference) ; BRN 1812518 ; MEDINA ; MEDINA (explosive) ; Methylene dinitramine ; N,N'-Dinitromethanediamine ; Methanediamine, N,N'-dinitro- .