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Cas Database |
| Name |
Mirosamicin |
EINECS | N/A |
| CAS No. | 73684-69-2 | Density | 1.22g/cm3 |
| PSA | 175.21000 | LogP | 1.76370 |
| Solubility | N/A | Melting Point |
104°C |
| Formula | C37H61 N O13 | Boiling Point | 843.2°C at 760 mmHg |
| Molecular Weight | 727.89 | Flash Point | 463.7°C |
| Transport Information | N/A | Appearance | N/A |
| Safety | Poison by intraperitoneal route. Moderately toxic by subcutaneous route. When heated to decomposition it emits toxic fumes of NOx. | Risk Codes | N/A |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
MycinamicinI, 14-hydroxy-; 4,17-Dioxabicyclo[14.1.0]heptadecane, mycinamicin I deriv.;Antibiotic A 11725II; Antibiotic AR 5-2; Miporamicin; Mirosamicin; Mirosamycin;Mycinamicin II; Mycinomycin II |
Article Data | 2 |
Mirosamicin Synthetic route
- 122825-79-0
mycinamicin II 3'-N-oxide
- 73684-69-2
mycinamicin II
| Conditions | Yield |
|---|---|
| With triphenylphosphine In dichloromethane at 55℃; for 67h; | 56% |
| Conditions | Yield |
|---|---|
| With multifunctional biosynthetic P450 monooxygenase; rhodococcus reductase domain; NADPH In aq. buffer at 28℃; for 2h; pH=7.3; Kinetics; Reagent/catalyst; Enzymatic reaction; | A 18.5% B n/a C n/a D n/a E n/a |
- 73684-72-7
mycinamicin V
- 73684-69-2
mycinamicin II
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 39 percent / MCPBA, disodium hydrogen phosphate / CH2Cl2 / 23 h / 60 °C 2: 56 percent / triphenylphosphine / CH2Cl2 / 67 h / 55 °C View Scheme |
Mirosamicin Chemical Properties
The IUPAC name of Mirosamicin (CAS NO.73684-69-2):
(1R,2S,3R,6E,8S,9S,10S,12R,14E,16R)-9-[(2S,3R,4S,6R)-4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl]oxy-3-ethyl-2-hydroxy-2-[[(2R,3R,4R,5R,6R)-5-hydroxy-3,4-dimethoxy-6-methyloxan-2-yl]oxymethyl]-8,10,12-trimethyl-4,17-dioxabicyclo[14.1.0]heptadeca-6,14-diene-5,13-dione
Synonyms: Miporamicin;A-11725II ; Antibiotic A-11725II ; Antibiotic AR-5-2 ; AR-5-2 ; Mycinamicin II
CAS: 73684-69-2
Molecular formula:C37H61NO13
Molecular Structure:
Molecular Weight 727.87914 g/mol
Index of Refraction: 1.545
Density: 1.22 g/cm3
Flash Point: 463.7 °C
Boiling Point: 843.2 °C at 760 mmHg
Mirosamicin Toxicity Data With Reference
The toxicity of Mirosamicin (CAS NO.73684-69-2):
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| mouse | LD50 | intraperitoneal | 363mg/kg (363mg/kg) | Journal of Antibiotics. Vol. 33, Pg. 364, 1980. | |
| mouse | LD50 | oral | 2gm/kg (2000mg/kg) | British UK Patent Application. Vol. #2020647A, | |
| mouse | LD50 | subcutaneous | 465mg/kg (465mg/kg) | Journal of Antibiotics. Vol. 33, Pg. 364, 1980. |
Mirosamicin Safety Profile
The safety information of Mirosamicin (CAS NO.73684-69-2):
Poison by intraperitoneal route. Moderately toxic by subcutaneous route. When heated to decomposition it emits toxic fumes of NOx.
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