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Basic Information
CAS No.: 13444-85-4
Name: nitrogen iodide
Molecular Structure:
Molecular Structure of 13444-85-4 (nitrogen iodide)
Formula: I3N
Molecular Weight: 394.72
Synonyms: Nitrogentriiodide
Density: 4.278g/cm3
Boiling Point: °Cat760mmHg
Flash Point: °C
Hazard Symbols: Explodes at slightest touch when dry; when handled it should be kept wet with ether. Too sensitive to be used as explosive, because it cannot be stored, handled, or transported safely.
Safety: A severe explosion hazard when shocked, exposed to heat or flame, or by spontaneous chemical reaction. It has no known uses as an explosive because it is far too sensitive in the dry state to store or handle safely. If this material must be worked with, it should be kept wet. A convenient way of keeping it wet is with ether; when it is needed in the dry state, it simply has to be taken out into the open and the ether will evaporate, leaving it perfectly dry. When dry, it will explode when given the slightest touch, vibration, or rise in temperature. Even a puff of air directed into it can cause it to detonate. It is a high explosive and is very violent. Incompatible with O3. H2S, Cl2, Br2, acids. See also IODIDES.
PSA: 3.24000
LogP: 2.33840
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Chemistry

Product Name: Nitrogen triiodide
Synonyms: Nitrogen triiodide ; Triiodamine ; Triiodoamine
CAS NO:13444-85-4
Molecular Formula of Nitrogen triiodide (CAS NO.13444-85-4) : I3N
Molecular Weight of Nitrogen triiodide (CAS NO.13444-85-4) :394.7201
Molecular Structure of Nitrogen triiodide (CAS NO.13444-85-4) :
Index of Refraction: 1.953
Surface Tension: 84.5 dyne/cm
Density: 4.278 g/cm3

Safety Profile

A severe explosion hazard when shocked, exposed to heat or flame, or by spontaneous chemical reaction. It has no known uses as an explosive because it is far too sensitive in the dry state to store or handle safely. If this material must be worked with, it should be kept wet. A convenient way of keeping it wet is with ether; when it is needed in the dry state, it simply has to be taken out into the open and the ether will evaporate, leaving it perfectly dry. When dry, it will explode when given the slightest touch, vibration, or rise in temperature. Even a puff of air directed into it can cause it to detonate. It is a high explosive and is very violent. Incompatible with O3. H2S, Cl2, Br2, acids. See also IODIDES.
RIDADR 0473
HazardClass 1.1A

Standards and Recommendations

DOT Classification:  Forbidden

Specification

Nitrogen triiodide is the inorganic compound with the formula NI3. It is an extremely sensitive contact explosive: small quantities explode with a gunpowder-like snap when touched even lightly, releasing a purple cloud of iodine vapor. NI3 has a complex structural chemistry that has required relatively heroic efforts to elucidate because of the instability of the derivatives.