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Cesium

Cesium General

Name:Cesium Symbol:Cs
Type: Alkali Metal Atomic weight:132.9055
Density @ 293 K:1.873 g/cm3 Atomic volume:71.07 cm3/mol
Discovered:

Cesium was discovered by Robert Bunsen and Gustav Kirchhoff in 1860, when they analyzed the spectrum of mineral water. Cesium was the first element discovered using a spectroscope. The origin of the name comes from the Latin word 'caesius', meaning sky blue. The Latin spelling is still reflected in British English where cesium is spelt caesium.

Cesium States

State (s, l, g):solid
Melting point:301.6 K (28.4 °C) Boiling point:943.2 K (670 °C)

Cesium Energies

Specific heat capacity:0.24 J g-1 K-1 Heat of atomization:76 kJ mol-1
Heat of fusion:2.092 kJ mol-1 Heat of vaporization :67.740 kJ mol-1
1st ionization energy: 375.7 kJ mol-1 2nd ionization energy: 2234.3 kJ mol-1
3rd ionization energy:3400 kJ mol-1 Electron affinity:45.506 kJ mol-1

Cesium Oxidation & Electrons

Shells:2,8,18,18,8,1 Electron configuration: [Xe] 6s1
Minimum oxidation number:0 Maximum oxidation number:3
Min. common oxidation no.:0 Max. common oxidation no.:3
Electronegativity (Pauling Scale): 0.79 Polarizability volume:59.6 Å3

Cesium Appearance & Characteristics

Structure:bcc: body-centered cubic Color:yellow/silvery
Hardness:0.2 mohs
Harmful effects:

Cesium must be kept under an inert liquid/gas or in a vacuum to protect it from air and water. Cesium compounds are considered to be mildy toxic.

Characteristics:

Cesium is silvery-gold, soft, ductile alkali metal. It is liquid in a warm room, melting at 28.4 °C(83.1 °F).

Cesium is one of the few metals that is liquid near room temperature. The others are gallium, francium and mercury.

Cesium is an extremely reactive metal and the most alkaline of the elements. It reacts explosively upon contact with water producing cesium hydroxide (CsOH), an extremely strong base that can rapidly corrode glass.


Uses:

Cesium is used in atomic clocks, which are incredibly accurate. NIST-F1, America's primary time and frequency standard, is a cesium fountain atomic clock developed at the NIST laboratories in Boulder, Colorado. NIST-F1 contributes to the international group of atomic clocks that define Coordinated Universal Time (UTC), the official world time. As scientists continue to improve its technology, uncertainty in NIST-F1's measurement of time is continually improving. Currently it neither gains nor loses as much a second in more than 60 million years - but see strontium. 

Cesium is also used in photoelectric cells and as a catalyst in the hydrogenation of organic compounds. The metal is used as a 'getter' in vacuum tubes.

Cesium hydroxide is used to etch silicon.

Cesium Reactions

Reaction with air:vigorous, ⇒ Cs2O Reaction with 6 M HCl:vigorous, ⇒ H2, CsCl
Reaction with 15 M HNO3:vigorous, ⇒ CsNO3 Reaction with 6 M NaOH:vigorous, ⇒ H2, CsOH

Cesium Compounds

Oxide(s):Cs2O, Cs2, Cs2O2 Chloride(s):CsCl
Hydride(s):CsH

Cesium Radius

Atomic radius:260 pm Ionic radius (1+ ion):181 pm
Ionic radius (2+ ion): pm Ionic radius (3+ ion): pm
Ionic radius (2- ion): pm Ionic radius (1- ion): pm

Cesium Conductivity

Thermal conductivity:35.9 W m-1 K-1 Electrical conductivity:5.3 x 106 S m-1

Cesium Abundance & Isotopes

Abundance earth's crust:3 parts per million by weight, 0.5 parts per million by moles
Abundance solar system: 8 parts per billion by weight, 70 parts per trillion by moles
Cost, pure:$1100 per 100g
Cost, bulk:$ per 100g
Source:

Cesium is found in the minerals pollucite and lepidolite. Commercially, most cesium is produced as a byproduct of the production of lithium metal. More than two-thirds of the world's reserves of Cesium - 110,000 tonnes - are found at Bernic Lake, Manitoba, Canada.

Isotopes:

Cesium has 36 isotopes whose half-lives are known, with mass numbers 112 to 148. Of these, one is stable: 133Cs.

Cesium Other

Other:

 


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