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Potassium dichromate

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Potassium dichromate

EINECS 231-906-6
CAS No. 7778-50-9 Density 2.676 g/cm3
PSA 117.97000 LogP -0.89720
Solubility 125 g/L (20 °C) in water Melting Point 398 °C
Formula Cr2H2O7 . 2K Boiling Point 500 °C
Molecular Weight 294.20 Flash Point 50°F
Transport Information UN 3086 6.1/PG 1 Appearance Orange red crystals
Safety 53-45-60-61-36/37-23-26 Risk Codes 45-46-60-61-8-21-25-26-34-42/43-48/23-50/53-52/53-20-48/20-23-51/53-22-36/37/38
Molecular Structure Molecular Structure of 7778-50-9 (Potassium dichromate(VI)) Hazard Symbols ToxicT, DangerousN, VeryT+, OxidizingO
Synonyms

Chromicacid (H2Cr2O7), dipotassium salt (9CI);Dichromic acid (H2Cr2O7), dipotassiumsalt (8CI);C 501;Chromium potassium oxide (K2Cr2O7);Dichromic aciddipotassium salt;Dipotassium bichromate;Dipotassium bichromate (K2Cr2O7);Dipotassium dichromate;Dipotassium dichromate (K2Cr2O7);Dipotassiumdichromium heptaoxide;Potassium bichromate;Potassium dichromate;Potassiumdichromate (K2(Cr2O7));Potassium dichromate(VI);SRM 935a;

 

Potassium dichromate Consensus Reports

IARC Cancer Review: Human Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 23 ,1980,p. 205.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 23 ,1980,p. 205.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Chromium and its compounds are on the Community Right-To-Know List. Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Potassium dichromate Standards and Recommendations

OSHA PEL: CL 0.1 mg(CrO3)/m3
ACGIH TLV: TWA 0.05 mg(CrO3)/m3
NIOSH REL: TWA (Chromium(VI)) 0.025 mg(Cr(VI))/m3; CL 0.05/15M

Potassium dichromate Analytical Methods

For occupational chemical analysis use NIOSH: Chromium Hexavalent, 7024.

Potassium dichromate Specification

The Potassium bichromate , with the CAS register number 7778-50-9, has other names as bichromateofpotash;chromicaci (h2cr2o7),dipotassiumsalt;chromicacid,dipotassiumsalt;chromicacid[h2cr2o7],dipotassiumsalt;dichromatedepotassium;Dichromicacid,dipotassiumsalt;dichromicacid[h2cr2o7],dipotassiumsalt;dichromicaciddipotassiumsalt .

It is a kind of orange red monoclinic system or triclinic system crystalline, and it is slightly soluble in water and easily soluble in hot water while insoluble in ethyl alcohol .

As for its usage, it is widely used in many field. First, it could be used as the chrome alum, chromium oxide green, chrome yellow pigment. Then, it could be mixed with the  feldspar powder and quartz sand to calcine and then comes enamel powder; It is used in modulating the match head to take the function of anti-moisture; It could be applied to as the tanning extracts and mordant in dyeing and printing; It could be used in making spice to be as oxidant. Besides, it is applied in welding rod, printing ink,passivation of metals and also as the oxidant and catalyst for organic synthesis and the raw material of the medicines.

It is a kind of very harmful chemical and you need to very cautious while dealing with it. Because it is dangerous for the environment, and it is toxic and oxidizing. Besides, it may cause cancer, heritable genetic damage, and impair fertility and it may cause harm to the unborn child, and etc. So take these instructions while using it. Wash hands, face, forearms and neck when exiting restricted areas; Wash hands before eating and do not eat, drink, or smoke in workplace; Wear special protective equipment for maintenance break-in or where exposures may exceed established exposure levels. Shower, dispose of outer clothing, change to clean garments at the end of the day; Protect against physical damage; Remove and dispose of any spilled dichromates; do not return to original containers;

When it comes to its storing, containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product; Store in a dry location separate from combustible, organic or other readily oxidizable materials. Avoid storage on wood floors.

What's more, its product categories are including the followings: inorganics;chromatesvolumetric solutions;n - r;oxidation;salt solutions;synthetic reagents;n - rvolumetric solutions;reference material sodium thiosolfatetitration;salt solutionsanalytical reagents;by reference material;solution containers (volpac);volumetric solutions;waste water;water test;reference material sodium thiosolfate;chromatesconcentrates (e.g. fixanal);concentrates (e.g. fixanal);reference material sodium thiosulfatetitration;salt concentrates.

Below are the toxicity information of this kind of chemcial:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
child LDLo oral 26mg/kg (26mg/kg) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

LUNGS, THORAX, OR RESPIRATION: RESPIRATORY STIMULATION

GASTROINTESTINAL: NAUSEA OR VOMITING
Zeitschrift fuer Kinderheilkunde. Vol. 81, Pg. 417, 1958.
child LDLo oral 50mg/kg (50mg/kg)   Gekkan Yakuji. Pharmaceuticals Monthly. Vol. 40, Pg. 2677, 1998.
dog LDLo oral 2829mg/kg (2829mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
 
dog LDLo unreported 2300ug/kg (2.3mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 27(12), Pg. 77, 1962.
guinea pig LDLo oral 163mg/kg (163mg/kg)   Zeitschrift fuer Kinderheilkunde. Vol. 81, Pg. 417, 1958.
guinea pig LDLo subcutaneous 29400ug/kg (29.4mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
 
man LDLo oral 143mg/kg (143mg/kg) VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION

LUNGS, THORAX, OR RESPIRATION: DYSPNEA

KIDNEY, URETER, AND BLADDER: URINE VOLUME DECREASED
Gekkan Yakuji. Pharmaceuticals Monthly. Vol. 40, Pg. 2677, 1998.
monkey LDLo subcutaneous 40mg/kg (40mg/kg) KIDNEY, URETER, AND BLADDER: "CHANGES IN TUBULES (INCLUDING ACUTE RENAL FAILURE, ACUTE TUBULAR NECROSIS)" American Journal of Pathology. Vol. 9, Pg. 133, 1933.
mouse LD50 intraperitoneal 37mg/kg (37mg/kg)   Carcinogenesis Vol. 4, Pg. 1535, 1983.
 
mouse LD50 oral 190mg/kg (190mg/kg)   Sangyo Igaku. Japanese Journal of Industrial Health. Vol. 20, Pg. 590, 1978.
mouse LDLo subcutaneous 100mg/kg (100mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
 
rabbit LD50 skin 14mg/kg (14mg/kg) LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA

SKIN AND APPENDAGES (SKIN): "DERMATITIS, OTHER: AFTER SYSTEMIC EXPOSURE"

GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"
National Technical Information Service. Vol. OTS0537040,
rabbit LDLo intravenous 27900ug/kg (27.9mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
 
rabbit LDLo subcutaneous 10mg/kg (10mg/kg) KIDNEY, URETER, AND BLADDER: "CHANGES IN TUBULES (INCLUDING ACUTE RENAL FAILURE, ACUTE TUBULAR NECROSIS)"

KIDNEY, URETER, AND BLADDER: INTERSTITIAL NEPHRITIS
Proceedings of the Society for Experimental Biology and Medicine. Vol. 9, Pg. 13, 1911.
rat LD50 intraperitoneal 28mg/kg (28mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. (5), Pg. 30, 1997.
 
rat LD50 oral 25mg/kg (25mg/kg) SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE

BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: ATAXIA
National Technical Information Service. Vol. OTS0545929,

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