Disulfide, 1,1-dimethylethyl phenyl

Base Information

• Chemical Name: Disulfide, 1,1-dimethylethyl phenyl
• CAS No.: 2943-20-6
• Molecular Formula: C10H14S2
• Molecular Weight: 198.353
• DSSTox Substance ID: DTXSID00450061
• Nikkaji Number: J448.257C
• Wikidata: Q82269631
• Mol file: 2943-20-6.mol

Synonyms:Disulfide, 1,1-dimethylethyl phenyl;2943-20-6;Phenyl tert-butyl persulfide;SCHEMBL776077;DTXSID00450061

Chemical Property of Disulfide, 1,1-dimethylethyl phenyl

Chemical Property:

• XLogP3: 3.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 198.05369279
• Heavy Atom Count: 12
• Complexity: 120

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)SSC1=CC=CC=C1

Technology Process of Disulfide, 1,1-dimethylethyl phenyl

There total 14 articles about Disulfide, 1,1-dimethylethyl phenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

4'-nitrobenzenesulfenanilide (64168-52-1) + 2-methylpropan-2-thiol (75-66-1) → 1-(tert-butyl)-2-phenyldisulfane (2943-20-6)

Guidance literature:

With potassium carbonate; boron trifluoride diethyl etherate; In dichloromethane; for 0.0333333h; Ambient temperature;

DOI:10.1016/S0040-4039(00)84361-0

Reference yield: 95.0%

(S)-t-butyl-p-toluenethiosulfinate (77329-76-1) → 4-methylbenzenesulfinyl chloride (10439-23-3) + 1-(tert-butyl)-2-phenyldisulfane (2943-20-6)

Guidance literature:

With benzenesulfenyl chloride; In chloroform-d1; at -10 ℃;

DOI:10.1016/S0040-4039(96)02096-5

Reference yield: 90.0%

N-phenylthiophthalimide (14204-27-4) + 2-methylpropan-2-thiol (75-66-1) → 1-(tert-butyl)-2-phenyldisulfane (2943-20-6)

Guidance literature:

In benzene; for 24h; Heating;

DOI:10.1021/ja00238a036

upstream raw materials:

t-butyl thionitrite

sodium thiophenolate

tert-Butyl thionitrate

N-phenylthiophthalimide

Downstream raw materials:

S-tert-butyl benzenesulfinothioate

S-phenyl 2-methylpropane-2-sulfinothioate