Phenol, 2-(1,1-dimethylethyl)-, phosphite

Base Information

• Chemical Name: Phenol, 2-(1,1-dimethylethyl)-, phosphite
• CAS No.: 31502-36-0
• Molecular Formula: C30H39O3P
• Molecular Weight: 478.612
• Mol file: 31502-36-0.mol

Synonyms:

Chemical Property of Phenol, 2-(1,1-dimethylethyl)-, phosphite

Chemical Property:

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Phenol, 2-(1,1-dimethylethyl)-, phosphite

There total 2 articles about Phenol, 2-(1,1-dimethylethyl)-, phosphite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-tert-Butylphenol (88-18-6) → tri(o-t-butylphenyl)phosphite (31502-36-0)

Guidance literature:

With triethylamine; phosphorus trichloride; In tetrahydrofuran; at 0 - 20 ℃; for 24h; Inert atmosphere;

DOI:10.1002/ejoc.201800604

Reference yield:

→ tri(o-t-butylphenyl)phosphite (31502-36-0)

Guidance literature:

entspr.Phenol, PCl3;

Reference yield: 100.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + tri(o-t-butylphenyl)phosphite (31502-36-0) → RhCl(CO)(P((OC(CH3)3)C6H4)3)2 (143192-20-5)

Guidance literature:

With CO; In dichloromethane; under N2; a stream of CO bubbled through soln. of Rh-compd., addn. of P-compd., gas evolution and changing of color; addn. of EtOH after 5 min, concd., filtered, washed (cold EtOH), dried; elem. anal.;

DOI:10.1021/om00059a015

upstream raw materials:

2-tert-Butylphenol

Downstream raw materials:

RhCl(CO)(P((OC(CH₃)3)C₆H₄)3)2

[Rh2(μ-S(CH2)2S)(CO)2(tris(2-t-butylphenyl) phosphite)2]

trans-[Rh2(μ-S(CH2)4S)(CO)2(tris(2-t-butylphenyl) phosphite)2]2

Ni(CO)2(P(OC₆H₄C(CH₃)3)3)2

Refernces

• 1、 Congmon, Jonathan,Tius, Marcus A.. "Contiguous Quaternary Centers from a AuI-Catalyzed Nazarov Cyclization". supporting information. p. 2926 - 2930. Retrieved 2018/06/27.