(1E)-1-(furan-2-ylmethylidene)-2-(4-nitrophenyl)hydrazine

Base Information

• Chemical Name: (1E)-1-(furan-2-ylmethylidene)-2-(4-nitrophenyl)hydrazine
• CAS No.: 3155-21-3
• Molecular Formula: C11H9N3O3
• Molecular Weight: 231.211
• European Community (EC) Number: 658-226-6
• DSSTox Substance ID: DTXSID00430681
• Mol file: 3155-21-3.mol

Synonyms:3155-21-3;(1E)-1-(furan-2-ylmethylidene)-2-(4-nitrophenyl)hydrazine;N-[(E)-furan-2-ylmethylideneamino]-4-nitroaniline;1-(Furan-2-ylmethylene)-2-(4-nitrophenyl)hydrazine;DTXSID00430681;STK000347;AKOS000485943;2-FURALDEHYDE (4-NITROPHENYL)HYDRAZONE

Chemical Property of (1E)-1-(furan-2-ylmethylidene)-2-(4-nitrophenyl)hydrazine

Chemical Property:

• XLogP3: 2.8
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 3
• Exact Mass: 231.06439116
• Heavy Atom Count: 17
• Complexity: 282

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=COC(=C1)C=NNC2=CC=C(C=C2)[N+](=O)[O-]
• Isomeric SMILES: C1=COC(=C1)/C=N/NC2=CC=C(C=C2)[N+](=O)[O-]

Technology Process of (1E)-1-(furan-2-ylmethylidene)-2-(4-nitrophenyl)hydrazine

There total 1 articles about (1E)-1-(furan-2-ylmethylidene)-2-(4-nitrophenyl)hydrazine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

furfural (98-01-1) + 4-nitrophenylhydrazone (100-16-3) → 1-(furan-2-ylmethylene)-2-(4-nitrophenyl)hydrazine (3155-21-3)

Guidance literature:

With acetic acid; In ethanol; for 0.166667h; Heating;

DOI:10.1016/S0040-4020(02)00552-5

Reference yield: 100.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + diethylamine (109-89-7) + 1-(furan-2-ylmethylene)-2-(4-nitrophenyl)hydrazine (3155-21-3) → diethyl-{2-furan-2-yl-2-[(4-nitro-phenyl)-hydrazono]-ethyl}-amine

Guidance literature:

In water; for 3h; Heating;

Reference yield: 88.0%

vinyl acetate (108-05-4,9003-20-7) + 1-(furan-2-ylmethylene)-2-(4-nitrophenyl)hydrazine (3155-21-3) → 3-(furan-2-yl)-1-(4-nitrophenyl)-4,5-dihydro-1H-pyrazol-5-yl acetate (1226895-88-0)

Guidance literature:

With chloroamine-T; In ethanol; at 80 ℃; Reflux;

DOI:10.1016/j.molstruc.2010.01.059

upstream raw materials:

furfural

4-nitrophenylhydrazone

Downstream raw materials:

2-furoylazo-p-nitrobenzene

3-(furan-2-yl)-1-(4-nitrophenyl)-5-phenyl-4,5-dihydro-1H-pyrazole

3-(furan-2-yl)-1-(4-nitrophenyl)-4,5-dihydro-1H-pyrazol-5-yl acetate

(3-(furan-2-yl)-1-(4-nitrophenyl)-1H-pyrazol-5-yl)methanol