2,2-Dibutyl-1,3,2-dioxastannolane

Base Information

Chemical Name:2,2-Dibutyl-1,3,2-dioxastannolane
CAS No.:3590-59-8
Molecular Formula:C10H22 O2 Sn
Molecular Weight:292.993
Hs Code.:2934999090
European Community (EC) Number:222-732-1
DSSTox Substance ID:DTXSID30189473
Mol file:3590-59-8.mol

Synonyms:2,2-Dibutyl-1,3,2-dioxastannolane;3590-59-8;2,2-Dibutyl-[1,3,2]dioxastannolane;EINECS 222-732-1;SCHEMBL830667;DTXSID30189473;1,1-dibutylstanna-2,5-dioxacyclopentane;NS00046981;1-di-n-butyl-1-stanna-2,5-dioxacyclopentane;2,2-Dibutyl-[1,3,2]dioxastannolane, 96%

Suppliers and Price of 2,2-Dibutyl-1,3,2-dioxastannolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
2,2-Dibutyl-[1,3,2]dioxastannolane 96%
10g
$ 186.00

Sigma-Aldrich
2,2-Dibutyl-[1,3,2]dioxastannolane 96%
5g
$ 115.00

American Custom Chemicals Corporation
2,2-DIBUTYL-[1,3,2]DIOXASTANNOLANE 95.00%
10G
$ 1261.26

American Custom Chemicals Corporation
2,2-DIBUTYL-[1,3,2]DIOXASTANNOLANE 95.00%
5G
$ 890.16

Total 10 raw suppliers

Chemical Property of 2,2-Dibutyl-1,3,2-dioxastannolane

Chemical Property:

Melting Point:231-236°C
Boiling Point:°Cat760mmHg
Flash Point:°C
PSA：18.46000
Density:g/cm³
LogP:3.07560
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:6
Exact Mass:294.064182
Heavy Atom Count:13
Complexity:123

Purity/Quality:

99% ^*data from raw suppliers

2,2-Dibutyl-[1,3,2]dioxastannolane 96% ^*data from reagent suppliers

Safty Information:

Pictogram(s): T
Hazard Codes:T
Statements: 25
Safety Statements: 45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Canonical SMILES:CCCC[Sn]1(OCCO1)CCCC
General Description 2,2-Dibutyl-1,3,2-dioxastannolane is a cyclic tin(IV) compound that forms five-coordinate trigonal bipyramidal complexes with ligands like pyridine or DMSO, where the tin center adopts an equatorial-apical configuration with the dioxastannolane ring bridging these positions. These complexes exhibit reversible ligand dissociation under reduced pressure, regenerating the parent compound. In solution, it predominantly exists as oligomers (dimers to pentamers) rather than monomers, with the oligomeric distribution being highly temperature-dependent. 2,2-dibutyl-1,3,2-dioxastannolane's stability is attributed to minimized angle strain in its five-membered ring, and its structural dynamics are influenced by reversible associative processes in nonpolar solvents.

Technology Process of 2,2-Dibutyl-1,3,2-dioxastannolane

There total 17 articles about 2,2-Dibutyl-1,3,2-dioxastannolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: dibutyltin(IV) oxide

: 107-21-1
ethylene glycol

: 3590-59-8
2,2-dibutyl[1,3,2]dioxastannolane

Guidance literature:: In cyclohexane; refluxing (2 h, azeotropic water removal), evapn., washing (EtOH); crystn. (toluene), drying (vac., 60°C);
DOI:10.1016/0022-328X(94)05356-G