α,α-Dimethylbenzyl azide

Base Information

• Chemical Name: α,α-Dimethylbenzyl azide
• CAS No.: 32366-26-0
• Molecular Formula: C9H11N3
• Molecular Weight: 161.206
• Mol file: 32366-26-0.mol

Synonyms:2-phenyl-2-propylazide;cumyl azide;2-phenylpropyl-2-azide;

Chemical Property of α,α-Dimethylbenzyl azide

Chemical Property:

• PSA: 49.75000
• LogP: 2.68476

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of α,α-Dimethylbenzyl azide

There total 11 articles about α,α-Dimethylbenzyl azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-phenyl-1-methyl-1-trimethylsiloxyethane (14629-57-3) → cumyl azide (32366-26-0)

Guidance literature:

With iron(III) chloride; trimethylsilylazide; In 1,2-dichloro-ethane; at 20 ℃; for 6h; Reagent/catalyst;

DOI:10.1002/chem.201202984

Reference yield: 96.0%

cumyl acetate (3425-72-7) → cumyl azide (32366-26-0)

Guidance literature:

With trimethylsilylazide; tris(pentafluorophenyl)borate; In tetrahydrofuran; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1080/00397911.2017.1350277

Reference yield: 92.0%

1-methyl-1-phenylethyl alcohol (617-94-7) → cumyl azide (32366-26-0)

Guidance literature:

With [Bmim]Cl-ZnCl₂; trimethylsilylazide; In dichloromethane; at 20 ℃; for 0.333333h; Inert atmosphere; Green chemistry;

DOI:10.1016/j.tetlet.2017.05.046

upstream raw materials:

1-methyl-1-phenylethyl alcohol

isopropenylbenzene

cumenyl chloride

phenylmagnesium bromide

Downstream raw materials:

2-phenyl-2-propylamine

N-(1-phenylethylidene)methanamine

N-(propan-2-ylidene)aniline

N-(2-phenylpropan-2-yl)-2-(trimethylsilyl)benzamide