14629-57-3

Basic information

• Product Name: 2-Phenyl-2-(trimethylsilyloxy)propane
• Synonyms: (α,α-Dimethylbenzyloxy)trimethylsilane;2-(Trimethylsilyloxy)-2-phenylpropane;2-Phenyl-2-(trimethylsilyloxy)propane;Trimethyl(1-methyl-1-phenylethyloxy)silane
• CAS NO: 14629-57-3
• Molecular Formula: C₁₂H₂₀OSi
• Molecular Weight: 208.37
• Mol File: 14629-57-3.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 43 °C(Press: 0.05 Torr)
• Appearance: /
• Density: 0.9501 g/cm3(Temp: 25 °C)
• CAS DataBase Reference: 2-Phenyl-2-(trimethylsilyloxy)propane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Phenyl-2-(trimethylsilyloxy)propane(14629-57-3)
• EPA Substance Registry System: 2-Phenyl-2-(trimethylsilyloxy)propane(14629-57-3)

Safety Data

• Hazardous Substances Data: 14629-57-3(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 3674-77-9 2-methyl-2-phenyl-1,3-dioxolane 
• 1450-14-2 1,1,1,2,2,2-hexamethyldisilane 
• 617-94-7 1-methyl-1-phenylethyl alcohol 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 
• 15681-48-8 lithium dimethylcuprate 
• 98-86-2 acetophenone 
• 102-85-2 tri-n-butyl phosphite 
• 18057-16-4 trimethylsilyl(cumyl) peroxide 
• 116-17-6 triisopropyl phosphite 
• 10416-59-8 N,O-bis-(trimethylsilyl)-acetamide 

Downstream Products

• 100-51-6 benzyl alcohol 
• 1233342-41-0 1,3-dimethoxy-4-(1-methyl-1-phenylethyl)benzene 
• 32366-26-0 cumyl azide 
• 617-94-7 1-methyl-1-phenylethyl alcohol 
• 1000-49-3 n-butyltrimethylsilane 

Relevant articles and documents

Simple procedure for the preparation of trimethylsilyl ethers of carbohydrates and alcohols

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Phase-Transfer Catalyzed O-Silyl Ether Deprotection Mediated by a Cyclopropenium Cation

The use of a cyclopropenium cation as a phase-transfer catalyst for O-silyl ether deprotection is reported. Mechanistic insight into this deprotection methodology derived by linear free-energy relationships (LFER), quantum theory of atoms in molecules (QTAIM), and density functional theory (DFT) calculations are also provided.

Gold nanoparticles-catalyzed activation of 1,2-disilanes: Hydrolysis, silyl protection of alcohols and reduction of tert-benzylic alcohols

Gold nanoparticles supported on TiO2 catalyze under mild conditions the activation of a series of 1,2-disilanes towards hydrolysis and alcoholysis, with concomitant evolution of H2 gas. For the case of tert-benzyl alcohols, the main or only pathway is reduction to the corresponding alkanes.