3-(3-Methylphenyl)prop-1-ene

Base Information

• Chemical Name: 3-(3-Methylphenyl)prop-1-ene
• CAS No.: 3333-20-8
• Molecular Formula: C10H12
• Molecular Weight: 132.205
• Hs Code.: 2902909090
• Mol file: 3333-20-8.mol

Synonyms:1-methyl-3-allylbenzene;3-Methyl-1-allylbenzol;1-Allyl-3-methyl-benzol;1-allyl-3-methylbenzene;meta-allyltoluene;m-allyltoluene;

Chemical Property of 3-(3-Methylphenyl)prop-1-ene

Chemical Property:

• Vapor Pressure: 1.12mmHg at 25°C
• Melting Point: 180 °C
• Refractive Index: n20/D1.511
• Boiling Point: 182.1oC at 760 mmHg
• Flash Point: 55.4oC
• PSA: 0.00000
• Density: 0.88g/cm3
• LogP: 2.72350

Purity/Quality:

98%,99%, ^*data from raw suppliers

3-(Allyl)toluene ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn
• Statements: 22

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of 3-(3-Methylphenyl)prop-1-ene

There total 16 articles about 3-(3-Methylphenyl)prop-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

allylisopropyl sulfide (50996-72-0) + m-tolylmagnesium bromide (28987-79-3) → 1-allyl-3-methylbenzene (3333-20-8)

Guidance literature:

With 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); In diethyl ether; for 10h; Heating;

DOI:10.1021/j100355a032

Reference yield: 73.0%

m-tolylboronic acid (17933-03-8) + allyl bromide (106-95-6) → 1-allyl-3-methylbenzene (3333-20-8)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In 1,2-dimethoxyethane; water; for 6h; Reflux;

DOI:10.1016/j.tetlet.2010.05.014

Reference yield: 58.0%

→ 1-allyl-3-methylbenzene (3333-20-8)

Guidance literature:

With [2,2]bipyridinyl; copper dichloride; In acetonitrile; for 24h; Inert atmosphere; Irradiation;

upstream raw materials:

allyl bromide

m-tolylmagnesium bromide

3-chloroprop-1-ene

toluene

Downstream raw materials:

β-methyl-3-methylstyrene

(E)-1-phenyl-2-(3-m-tolylallyl)butane-1,3-dione

(E)-3-(3-tolyl)acrylic acid n-butyl ester

Refernces

• 1、 -. "Aryl C-F bond functionalization preparation method". Paragraph 0052; 0054-0061. . Retrieved 2021/09/29.
• 2、 Qi, Xiaoxu,Chen, Pinhong,Liu, Guosheng. "Catalytic Oxidative Trifluoromethoxylation of Allylic C?H Bonds Using a Palladium Catalyst". supporting information. p. 9517 - 9521. Retrieved 2017/08/01.