(triphos)Fe(CO)H₂

Base Information

Chemical Name:(triphos)Fe(CO)H₂
CAS No.:1079337-96-4
Molecular Formula:C₄₂H₄₁FeOP₃
Molecular Weight:710.555
Hs Code.:

Synonyms:

Suppliers and Price of (triphos)Fe(CO)H₂

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (triphos)Fe(CO)H₂

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (triphos)Fe(CO)H₂

There total 1 articles about (triphos)Fe(CO)H₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

: 16940-66-2
sodium tetrahydroborate

: hexaaquairon(II) tetrafluoroborate

: 201230-82-2
carbon monoxide

: 22031-12-5
[2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]

: 1079337-96-4
(triphos)Fe(CO)H₂

Guidance literature:: In tetrahydrofuran; ethanol; (under inert atm., Schlenk); soln. of NaBH4 in EtOH added to soln. of Fe-complex and ligand in THF, refluxed for 20 min, filtered, CO passed through soln. for 10 min; layered with hexane, stored at -40°C for 1 d, soln. reduced in vacuo, decanted, dried in vacuo, recrystd. from mixt. of CH2Cl2-EtOH;
DOI:10.1039/b801652f

Reference yield:

: 599-00-8
trifluoroacetic acid-d₁

: 1079337-96-4
(triphos)Fe(CO)H₂

: (triphos)Fe(CO)(η-H(2)H)H(1+)

: (triphos)Fe(CO)(η-H(2)H)(2)H(1+)

Guidance literature:: In dichloromethane-d2; (under inert atm., Schlenk); soln. of Fe-complex in CD2Cl2 charged NMR tube, CF3CO2D added at -78°C, maintained at 180 K; monitored by NMR;
DOI:10.1039/b801652f

Reference yield:

: 920-66-1
1,1,1,3',3',3'-hexafluoro-propanol

: 1079337-96-4
(triphos)Fe(CO)H₂

: 1079338-00-3
(triphos)Fe(CO)(η-H2)H(CF3)2CHO

Guidance literature:: In dichloromethane-d2; (under inert atm., Schlenk); soln. of Fe-complex in CD2Cl2 charged NMR tube, (CF3)2CHOH added at -78°C, maintained at 180 K; monitored by NMR;
DOI:10.1039/b801652f