1-Chloro-2,4-hexadiene

Base Information

• Chemical Name: 1-Chloro-2,4-hexadiene
• CAS No.: 34632-89-8
• Molecular Formula: C6H9Cl
• Molecular Weight: 116.59
• Hs Code.: 2903299090
• Mol file: 34632-89-8.mol

Synonyms:sorbyl chloride;1-chloro-2,4-hexadiene;1-chloro-hexa-2t,4t-diene;(E,E)-1-chlorohexa-2,4-diene;2,4-hexadienyl chloride;

Chemical Property of 1-Chloro-2,4-hexadiene

Chemical Property:

• Vapor Pressure: 6.15mmHg at 25°C
• Boiling Point: 45.5 °C(Press: 12 Torr)
• PSA: 0.00000
• Density: 0.9434 g/cm3(Temp: 24 °C)
• LogP: 2.35750

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-Chloro-2,4-hexadiene

There total 9 articles about 1-Chloro-2,4-hexadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,4-hexadiene-1-ol (111-28-4) → 2,4-hexadienyl chloride (34632-89-8)

Guidance literature:

With pyridine; thionyl chloride; diethyl ether; at 0 ℃;

Reference yield:

Sorbyl alcohol (17102-64-6) → (2E,4E)-1-chlorohexa-2,4-diene (34632-89-8,17100-75-3)

Guidance literature:

With N-chloro-succinimide; dimethylsulfide; In dichloromethane; at -20 - 20 ℃; for 2h; Inert atmosphere;

DOI:10.1039/c3cc45879b

Reference yield:

ethyl hexa-2,4-dienoate (2396-84-1) → 2,4-hexadienyl chloride (34632-89-8)

Guidance literature:

Multi-step reaction with 2 steps

1: LiAlH₄ / diethyl ether

2: SOCl₂, Py, ZnCl₂ / diethyl ether

With pyridine; lithium aluminium tetrahydride; thionyl chloride; zinc(II) chloride; In diethyl ether;

upstream raw materials:

2,4-hexadiene-1-ol

3,5-hexadien-2-ol

hydrogenchloride

diethyl ether

Downstream raw materials:

n-hexan-2-ol

hexan-1-ol

2,4-hexadiene-1-ol

3,5-hexadien-2-ol

Refernces