2,4-Dimethoxybenzophenone

Base Information

• Chemical Name: 2,4-Dimethoxybenzophenone
• CAS No.: 3555-84-8
• Molecular Formula: C15H14O3
• Molecular Weight: 242.274
• Hs Code.: 2914509090
• Mol file: 3555-84-8.mol

Synonyms:Methanone, (2,4-dimethoxyphenyl)phenyl-;2,4-dimethoxy-benzophenone;2,4-dimethoxyphenyl phenyl ketone;DIMETHOXYBENZOPHENONE;

Chemical Property of 2,4-Dimethoxybenzophenone

Chemical Property:

• Melting Point: 87.5°C
• Refractive Index: 1.5570 (estimate)
• Boiling Point: 345.09°C (rough estimate)
• PSA: 35.53000
• Density: 1.1515 (rough estimate)
• LogP: 2.93480

Purity/Quality:

95% ^*data from raw suppliers

(2,4-Dimethoxy-phenyl)-phenyl-methanone ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2,4-Dimethoxybenzophenone

There total 34 articles about 2,4-Dimethoxybenzophenone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

benzoyl chloride (98-88-4) + 1,3-Dimethoxybenzene (151-10-0) → 2,4-dimethoxybenzophenone (3555-84-8)

Guidance literature:

With bismuth(lll) trifluoromethanesulfonate; for 0.0833333h; Ionic liquid; Microwave irradiation;

DOI:10.1016/j.tetlet.2011.11.022

Reference yield: 97.0%

benzoic acid anhydride (93-97-0) + 1,3-Dimethoxybenzene (151-10-0) → 2,4-dimethoxybenzophenone (3555-84-8)

Guidance literature:

With bismuth(lll) trifluoromethanesulfonate; for 0.0833333h; Ionic liquid; Microwave irradiation;

DOI:10.1016/j.tetlet.2011.11.022

Reference yield: 97.0%

benzoic acid (65-85-0,8013-63-6) + 1,3-Dimethoxybenzene (151-10-0) → 2,4-dimethoxybenzophenone (3555-84-8)

Guidance literature:

With pyridin-2-yl trifluoromethanesulfonate; trifluoroacetic acid; for 5h; Heating;

DOI:10.1246/bcsj.61.455

upstream raw materials:

benzoyl chloride

1,3-Dimethoxybenzene

N-phenyl-benzimidoyl chloride

2.4-dihydroxybenzophenone

Downstream raw materials:

2.4-dihydroxybenzophenone

Benzophenone-3

2,4-Dimethoxy-benzhydrol

2,4-dimethoxy-benzophenone oxime

Refernces

• 1、 Kim, Hyunseok,Park, Sangjune,Baek, Yonghyeon,Um, Kyusik,Han, Gi Uk,Jeon, Da-Hye,Han, Sang Hoon,Lee, Phil Ho. "Synthesis of diaryl ketones through oxidative cleavage of the C-C double bonds in N -Sulfonyl enamides". . p. 3486 - 3496. Retrieved 2018/04/14.
• 2、 Pandey, Ganesh,Tiwari, Sandip Kumar,Singh, Bhawana,Vanka, Kumar,Jain, Shailja. "P -Selective (sp2)-C-H functionalization for an acylation/alkylation reaction using organic photoredox catalysis". supporting information. p. 12337 - 12340. Retrieved 2017/11/20.