Isobutylidenemalonic acid dimethyl ester

Base Information

Chemical Name:Isobutylidenemalonic acid dimethyl ester
CAS No.:36825-11-3
Molecular Formula:C9H14O4
Molecular Weight:186.208
Hs Code.:
Mol file:36825-11-3.mol

Synonyms:Dimethyl (2-methylpropylidene)malonate;Dimethyl 2-(2-methylpropylidene)malonate;dimethyl isobutylidenenemalonate;Propanedioic acid,(2-methylpropylidene)-,dimethyl ester;methyl 4,4-dimethyl-2-(methoxycarbonyl)-2-pentenoate;2-isobutylidene malonic acid dimethyl ester;

Suppliers and Price of Isobutylidenemalonic acid dimethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
2-ISOBUTYLENEMALONIC ACID DIMETHYL ESTER 95.00%
5MG
$ 498.95

Total 2 raw suppliers

Chemical Property of Isobutylidenemalonic acid dimethyl ester

Chemical Property:

PSA：52.60000
LogP:0.91480

Purity/Quality:

98% ^*data from raw suppliers

2-ISOBUTYLENEMALONIC ACID DIMETHYL ESTER 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Isobutylidenemalonic acid dimethyl ester

There total 1 articles about Isobutylidenemalonic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 6773-29-1
dimethyl diazomalonate

: 78-84-2
isobutyraldehyde

: 36825-11-3
2-isobutylidene malonic acid dimethyl ester

Guidance literature:: With tributylstibine; copper(l) iodide; In benzene; at 70 ℃; for 4h;
DOI:10.1016/S0040-4039(00)97988-7

Reference yield: 88.0%

: 36825-11-3
2-isobutylidene malonic acid dimethyl ester

: 81167-39-7
methyl N-(diphenylmethylene)glycinate

: 1259433-65-2
C₂₅H₂₉NO₆

Guidance literature:: With (2-(bis(3,5-bis(trifluoromethyl)phenyl)phosphino)-3-((S)-4-isopropyl-4,5-dihydrooxazol-2-yl)cyclopenta-2,4-dien-1-yl)(cyclopenta-2,4-dien-1-yl)iron; potassium tert-butylate; copper(II) bis(trifluoromethanesulfonate); isopropyl alcohol; In tetrahydrofuran; at 0 ℃; for 8h; optical yield given as %ee; stereoselective reaction; Molecular sieve; Inert atmosphere;
DOI:10.1002/cjoc.201090297